VUsing 'H NMR data of both your product and the starting material (p-toluic acid), describe hovsupports the formation of 4-bromomethylbenzoic acid.Hint: use chemical shift and integratiorresponse. AD 2_9 22Temperature 25Spectrometer nmr.bard.edu-vnmrs400Study owner CHEM202Operator CHEM202Sample Name AD 2_9_22Pulse sequernce PROTONDate collected 2022-02-09Solvent dmsoINTEGRAL VALUESIntegralstan(ppm)endvalueANSPOSETI13.098412.1937.5582810.9928.049381.974SS PIPEORGAN37.481557.097881.9942.417162.217653.041PEAK FREUENCIESindexfreg(ppm)intensity7.8051941.02317.7856141.63253.7.2746338.9297.2540734.80633.29542132.32.46825140.6272.46434154.7722.33414129.6671412108.6.42ppm3No BromnePlot dale 2022-02-09Data file /horne/Research/vnmrsys/data CHEM202/CHEM202_AD_2_9_ 22_20220209_01/AD_2_9_22_PROTON_01 TolulcAcidSample Namme TolulcAcldDate collected 2022-02-08Pulse sequence PROTONSovent dmsoTemperature 25Spectrometer nmr.bard.edu-vnmrs400Study owner CHEM202Operator CHEM202DMSOçoOHCH3P-toluic acid11104.1ppm1312.023.29

V Using 'H NMR data of both your product and the starting material (p-toluic acid), describe hov supports the formation of 4-bromomethylbenzoic acid. Hint: use chemical shift and integratior response.

V Using 'H NMR data of both your product and the starting material (p-toluic acid), describe hov supports the formation of 4-bromomethylbenzoic acid. Hint: use chemical shift and integratior response.

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter12: Nuclear Magnetic Resonance Spectroscopy

Section: Chapter Questions

Problem 3Q

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Concept explainers

Mass Spectrometry

This process is an instrumental method in which a sample is changed to fast moving positive ions by electron bombardment. The charged particles vary due to their different mass to charge ratio and are estimated with the help of this difference. It is also called mass spectroscopy.

Question

AD 2_9 22
Temperature 25
Spectrometer nmr.bard.edu-vnmrs400
Study owner CHEM202
Operator CHEM202
Sample Name AD 2_9_22
Pulse sequernce PROTON
Date collected 2022-02-09
Solvent dmso
INTEGRAL VALUES
Integral
stan(ppm)
end
value
ANSPOSE
TI
13.0984
12.193
7.55828
1
0.992
8.04938
1.974
SS PIPE
ORGAN
3
7.48155
7.09788
1.994
2.41716
2.21765
3.041
PEAK FREUENCIES
index
freg(ppm)
intensity
7.80519
41.0231
7.78561
41.6325
3.
7.27463
38.929
7.25407
34.8063
3.29542
132.3
2.46825
140.627
2.46434
154.772
2.33414
129.667
14
12
10
8.
6.
4
2
ppm
3
No Bromne
Plot dale 2022-02-09
Data file /horne/Research/vnmrsys/data CHEM202/CHEM202_AD_2_9_ 22_20220209_01/AD_2_9_22_PROTON_01

TolulcAcid
Sample Namme TolulcAcld
Date collected 2022-02-08
Pulse sequence PROTON
Sovent dmso
Temperature 25
Spectrometer nmr.bard.edu-vnmrs400
Study owner CHEM202
Operator CHEM202
DMSO
çoOH
CH3
P-toluic acid
11
10
4.
1
ppm
13
12
.02
3.29

Expert Solution

Step 1: Introduction

Nuclear magnetic resonance (NMR) is the characteristics of nuclei which is the dependent on the applied external magnetic field.

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