Consider the reaction between oxygen and nitrogen monoxide, a key step in the formation of acid rain: O2 (g) + 2 NO (g)=> 2 NO2 (g) The following experimental data were obtained in studying the kinetic of this reaction: Experiment Initial Rate, M/s Initial [O2] Initial [NO] 1 3.21 x 10-3 1.10 x 10-2 1.30 x 10-2 2 6.40 x 10-3 2.20 x 10-2 1.30 x 10-2 3 12.8 x 10-3 1.10 x 10-2 2.60 x 10-2 4 9.60 x 10-3 3.30 x 10-2 1.30 x 10-2 5 28.8 x 10-3 1.10 x 10-2 3.90 x 10-2

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
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Consider the reaction between oxygen and nitrogen monoxide, a key step in the formation of acid rain:

                                                  O2 (g)   +   2 NO (g)=>  2 NO2 (g)

            The following experimental data were obtained in studying the kinetic of this reaction:

           

Experiment

Initial Rate, M/s

Initial [O2]

Initial [NO]

1

3.21 x 10-3

1.10 x 10-2

1.30 x 10-2

2

6.40 x 10-3

2.20 x 10-2

1.30 x 10-2

3

12.8 x 10-3

1.10 x 10-2

2.60 x 10-2

4

9.60 x 10-3

3.30 x 10-2

1.30 x 10-2

5

28.8 x 10-3

1.10 x 10-2

3.90 x 10-2

 

  1. Determine the rate law for this reaction 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

  1. Calculate the rate constant for the reaction 

 

 

 

 

 

What is the rate of the reaction if the [O2] and [NO] are both 0.50 M. 

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