Consider the reaction Mn+ + ne- ⇌ M. If ΔG*c = ΔG* + (1-α)nFE and η = E – Eeq, prove that ic = io exp[-(1-α)nFηa)/RT)].

Consider the reaction Mn+ + ne- ⇌ M. If ΔGc = ΔG + (1-α)nFE and η = E – Eeq, prove that ic = io exp[-(1-α)nFηa)/RT)].

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter12: Chemical Kinetics

Section: Chapter Questions

Problem 91AE: For the reaction 2N2O5(g)4NO2(g)+O2(g) the following data were collected, where Rate=[N2O5]t Time...

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Consider the reaction Mn+ + ne- ⇌ M. If ΔG*c = ΔG* + (1-α)nFE and η = E – Eeq, prove that ic = io exp[-(1-α)nFηa)/RT)].

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