Consider the reaction: OCl-(aq) +/-(aq) → 01-(aq) + Cl-(aq) rate = k[0CI¯]*[I¯]°[0H¯]² Use the method of initial rates along with the following data to determine the reaction orders and the rate constant for this reaction. Note that the reaction orders are not necessarily integers. [OCt"], (M) 1.62 x 10 1.62 x 103 2.71 x 10 1.62 x 103 [ (M) 1.62 x 103 2.88 x 10-3 1.62 x 103 2.88 x 10 rate (M/s) 3.06 х 104 5.44 x 104 3.16 x 104 [OH], (M) 0.52 0.52 0.84 0.91 3.11 x 104

Chemistry for Engineering Students
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Chapter11: Chemical Kinetics
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Problem 11.51PAE: 11.51 Peroxyacetyl nitrate (PAN) has the chemical formula CtHjNOj and is an important lung irritant...
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OC-(aq) +1-(aq) → 01-(aq) + Ci-(aq)
rate = k[0Cl-]*[I¯]P[0H¯]²
Use the method of initial rates along with the following data to determine the reaction orders
and the rate constant for this reaction, Note that the reaction orders are not necessarily
Consider the reaction:
integers.
[Oct ], (M)
1.62 x 10
1.62 x 10
2.71 x 10
1.62 x 10
[1-], (M)
1.62 x 10
2.88 x 10
1.62 x 103
2.88 x 10
[OH ], (M)
0.52
0.52
rate, (M/s)
3.06 х 104
5.44 x 104
3.16 х 104
3.11 x 104
0.84
0.91
Transcribed Image Text:OC-(aq) +1-(aq) → 01-(aq) + Ci-(aq) rate = k[0Cl-]*[I¯]P[0H¯]² Use the method of initial rates along with the following data to determine the reaction orders and the rate constant for this reaction, Note that the reaction orders are not necessarily Consider the reaction: integers. [Oct ], (M) 1.62 x 10 1.62 x 10 2.71 x 10 1.62 x 10 [1-], (M) 1.62 x 10 2.88 x 10 1.62 x 103 2.88 x 10 [OH ], (M) 0.52 0.52 rate, (M/s) 3.06 х 104 5.44 x 104 3.16 х 104 3.11 x 104 0.84 0.91
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