Consider the reversible reaction A to B,k1 Bto A,k-1 in which [A]0=1.0 M and [B]0=0. Make a plot of [A] and [B] vs. time for k1=6.0 s-1 and k-1 = 4.0 s-1. From your plot determine: (a) the time a which [A]=[B]. (b) the equilibrium values for [A] and [B] (c) Show that the equilibrium constant for the reaction under these conditions is related the values of k1 and k2 in the expected way.
Consider the reversible reaction A to B,k1 Bto A,k-1 in which [A]0=1.0 M and [B]0=0. Make a plot of [A] and [B] vs. time for k1=6.0 s-1 and k-1 = 4.0 s-1. From your plot determine: (a) the time a which [A]=[B]. (b) the equilibrium values for [A] and [B] (c) Show that the equilibrium constant for the reaction under these conditions is related the values of k1 and k2 in the expected way.
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.84P
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Question
. Consider the reversible reaction
A to B,k1
Bto A,k-1
in which [A]0=1.0 M and [B]0=0. Make a plot of [A] and [B] vs. time for k1=6.0 s-1 and k-1 = 4.0 s-1. From your plot determine:
(a) the time a which [A]=[B].
(b) the equilibrium values for [A] and [B]
(c) Show that the equilibrium constant for the reaction under these conditions is related the values of k1 and k2 in the expected way.
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