Consider the table of equilibrium constant values given below for a given set of conditions. What will be the concentration of [HCO3-] in water that is in equilibrium with both CaCO3 (s) and 225 ppm CO2 (g) under these conditions? Equation Type Value CO2 (g) H2CO3 (aq) KH 1.7 x 102 H2CO3 (aq)=HCO3(aq) + H (aq) Kat 6.44 x 107 HCO3 (aq) CO32 (aq) + H* (aq) Ka2 8.43 x 10-11 CaCO3 (s) Ca2+ (aq) + CO2 (aq) Ksp 8.4 x 10-9 H₂O (1) H(aq) + OH (aq) Kw 7.6 x 10-14 O 1.6 x 103 M O 8.1 x 10-3 M O 5.6 x 104 M O 3.9 x 104 M O 7.9 x 104 M

Chemistry: Principles and Reactions
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Chapter15: Complex Ion And Precipitation Equilibria
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Consider the table of equilibrium constant values given below for a given set of conditions. What will be the concentration of
[HCO3-] in water that is in equilibrium with both CaCO3 (s) and 225 ppm CO2 (g) under these conditions?
Equation
Type
Value
CO2 (g) H2CO3 (aq)
KH
1.7 x 102
H2CO3 (aq)=HCO3(aq) + H (aq)
Kat
6.44 x 107
HCO3 (aq) CO32 (aq) + H* (aq)
Ka2
8.43 x 10-11
CaCO3 (s)
Ca2+ (aq) + CO2 (aq)
Ksp
8.4 x 10-9
H₂O (1)
H(aq) + OH (aq)
Kw
7.6 x 10-14
O 1.6 x 103 M
O 8.1 x 10-3 M
O 5.6 x 104 M
O 3.9 x 104 M
O 7.9 x 104 M
Transcribed Image Text:Consider the table of equilibrium constant values given below for a given set of conditions. What will be the concentration of [HCO3-] in water that is in equilibrium with both CaCO3 (s) and 225 ppm CO2 (g) under these conditions? Equation Type Value CO2 (g) H2CO3 (aq) KH 1.7 x 102 H2CO3 (aq)=HCO3(aq) + H (aq) Kat 6.44 x 107 HCO3 (aq) CO32 (aq) + H* (aq) Ka2 8.43 x 10-11 CaCO3 (s) Ca2+ (aq) + CO2 (aq) Ksp 8.4 x 10-9 H₂O (1) H(aq) + OH (aq) Kw 7.6 x 10-14 O 1.6 x 103 M O 8.1 x 10-3 M O 5.6 x 104 M O 3.9 x 104 M O 7.9 x 104 M
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