Constants Periodic TableZinc metal reacts with hydrochloric acid accordingto the following balanced equation.Zn(s) + 2HC1(aq)→ZnCl2 (aq) + H2 (g)When 0.112 g of Zn(s) is combined with enoughHCl to make 515 mL of solution in a coffee-cupcalorimeter, all of the zinc reacts, raising thetemperature of the solution from 22.1 C to 241°C.Part AFind A H for this reaction as written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g. C asthe specific heat capacity.)να ΑΣφAH,xn -kJ/molSubmitPrevious Answers Request Answer* Incorrect; Try Again; 25 attempts remainingNext >Provide FeedbackP 8:36

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Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter4: Stoichiometry

Section: Chapter Questions

Problem 4.58PAE

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4-77 To convert 1 mol of iron(III) oxide to its elements requires 196.5 kcal: How many grams of iron can be produced if 156.0 kcal of heat is absorbed by a large-enough sample of iron(III) oxide?
Many over-the-counter antacid tablets are now formulated using calcium carbonate as die active ingredient, which enables such tablets to also be used as dietary calcium supplements. As an antacid for gastric hyperacidity, calcium carbonate reacts by combining with hydrochloric acid found in the stomach, producing a solution of calcium chloride, converting die stomach acid to water, and releasing carbon dioxide gas (which the person suffering from stomach problems may feel as a burp). Write die balanced chemical equation for this process.
A rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.
A power plant is driven by the combustion of a complex fossil fuel having the formula C11H7S. Assume the air supply is composed of only N2 and O2 with a molar ratio of 3.76:1.00, and the N2 remains unreacted. In addition to the water produced, the fuels C is completely combusted to CO2 and its sulfur content is converted to SO2. In order to evaluate gases emitted at the exhaust stacks for environmental regulation purposes, the nitrogen supplied with the air must also be included in the balanced reactions. a Including the N2 supplied m the air, write a balanced combustion equation for the complex fuel assuming 100% stoichiometric combustion (i.e., when there is no excess oxygen in the products and the only C-containing product is CO2). Except in the case of N2, use only integer coefficients. b Including N2 supplied in the air, write a balanced combustion equation for the complex fuel assuming 120% stoichiometric combustion (i.e., when excess oxygen is present in the products and the only C-containing product is CO2). Except in the case of use only integer coefficients c Calculate the minimum mass (in kg) of air required to completely combust 1700 kg of C11H7S. d Calculate the air/fuel mass ratio, assuming 100% stoichiometric combustion. e Calculate the air/fuel mass ratio, assuming 120% stoichiometric combustion.
Insoluble AgCl(s) precipitates when solutions of AgNO3(aq) and NaCl(aq) are mixed. AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq) rH = ? To measure the energy evolved in this reaction, 250. mL of 0.16 M AgNO3(aq) and 125 mL of 0.32 M NaCl(aq) are mixed in a coffee-cup calorimeter. The temperature of the mixture rises from 21.15 C to 22.90 C. Calculate the enthalpy change for the precipitation of AgCl(s), in kJ/mol. (Assume the density of the solution is 1.0 g/mL and its specific heat capacity is 4.2 J/g K.)
Carbon dioxide from the atmosphere weathers, or dissolves, limestone (CaCO3) by the reaction CaCO3(s)+CO2(g)+H2O(l)Ca2(aq)+2HCO3(aq) Obtain H for this reaction. See Table 6.2 for the data.
The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.
Many over-the-counter antacid tablets are now formulated using calcium carbonate as the active ingredient, which enables such tablets to also be used as dietary calcium supplements. As an antacid for gastric hyperacidity, calcium carbonate reacts by combining with hydrochloric acid found in the stomach, producing a solution of calcium chloride, converting the stomach acid to water, and releasing carbon dioxide gas (which the person suffering from stomach problems may feel as a “burp”). Write the unbalanced chemical equation for this process.
When corn is allowed to ferment, the fructose in the corn is converted to ethyl alcohol according to the following reaction C6H12O6(aq)2C2H5OH(l)+2CO2(g)(a) What volume of ethyl alcohol (d=0.789g/mL) is produced from one pound of fructose? (b) Gasohol can be a mixture of 10 mL ethyl alcohol and 90 mL of gasoline. How many grams of fructose are required to produce the ethyl alcohol in one gallon of gasohol?
4.3 Explain the difference between complete and incomplete combustion.
he production capacity for acrylonitrile (C3H3N)in the United States is over 2 billion pounds per year. Acrylonitrile, the building block tor acrylonitrile fibers and a variety of plastics, is produced from gaseous propylene, ammonia, and oxygen: :math>2C3H6(g)+2NH3(g)+3O22C3H3N(g)+6H2O(g) l type='a'> Assuming 100% yield, determine the mass of acrylonitrile which can be produced from the mixture below: l> Mass Reactant msp;5.23102g propylene td> msp;5.00102g ammonia td> msp;1.00103g oxygen td> i>What mass of water is formed from your mixture? Calculate the mass (in grams) of each reactant after the reaction is complete.
Suppose that you are closing a cabin in the north woods for the winter and you do not want the water in the toilet tank to freeze. You know that the temperature might get as low as 30. C, and you want to protect about 4.0 L water in the toilet tank from freezing. Calculate the volume of ethylene glycol (density = 1.113 g/mL; molar mass = 62.1 g/mol) you should add to the 4.0 L water.

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