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Copper normally melts at 1085 °C with an enthalpy of melting of 13.05 kj/mole. The constant molar volumes of liquid and solid copper are 8×10^-6 and 7.6×10^-6 m^3, respectively. a) Estimate the change in melting point if the pressure on copper is increased 10 atm. (Use Clapeyron equation) b) Draw G vs. P graphs for solid and liquid copper (show them on the same graph) at a given constant temperature. Indicate the slopes.

Copper normally melts at 1085 °C with an enthalpy of melting of 13.05 kj/mole. The constant molar volumes of liquid and solid copper are 8×10^-6 and 7.6×10^-6 m^3, respectively. a) Estimate the change in melting point if the pressure on copper is increased 10 atm. (Use Clapeyron equation) b) Draw G vs. P graphs for solid and liquid copper (show them on the same graph) at a given constant temperature. Indicate the slopes.

Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter9: Liquids And Solids
Section: Chapter Questions
Problem 106E
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Copper normally melts at 1085 °C with an enthalpy of melting of 13.05 kj/mole. The constant molar volumes of liquid and solid copper are 8×10^-6 and 7.6×10^-6 m^3, respectively. a) Estimate the change in melting point if the pressure on copper is increased 10 atm. (Use Clapeyron equation) b) Draw G vs. P graphs for solid and liquid copper (show them on the same graph) at a given constant temperature. Indicate the slopes.
Transcribed Image Text:Copper normally melts at 1085 °C with an enthalpy of melting of 13.05 kj/mole. The constant molar volumes of liquid and solid copper are 8×10^-6 and 7.6×10^-6 m^3, respectively. a) Estimate the change in melting point if the pressure on copper is increased 10 atm. (Use Clapeyron equation) b) Draw G vs. P graphs for solid and liquid copper (show them on the same graph) at a given constant temperature. Indicate the slopes.
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