Copy the figure shown below onto your scratch paper. Box 1 Вох 2 Box 3 HBr Br Then, complete the figure on your scratch paper by drawing out the intermediates and arrow-pushing mechanism in Boxes 1-3 that explain the formation of the final products shown. You should start your arrow-pushing in Box 1, and you will use all boxes. Now, report formal charges (+,0,-) that appear on the alpha carbon, beta carbon, and bromine atoms in each box, and match the contents of each box to a single phrase (A-H) that best describes the mechanistic step that occurs in each box. A. A hydride shift occurs. B. A methyl shift occurs. C. A nucleophile attacks a tertiary carbocation. D. A leaving group leaves. E. A nucleophile attacks a secondary carbocation. F. Br is protonated, the alpha carbon is deprotonated, and a pi bond forms G. A carbocation attacks the Br. H. Br is protonated, the beta carbon is deprotonated, and a pi bond forms Ca formal charge (+.0,-) Ce formal charge (+,0.-) Br formal charge (+,0.-) Phrase (A-H) Box 1: 0 Box 2: Вох 3: Products: 0

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter21: Nas: Nucleophilic Aromatic Substitution
Section: Chapter Questions
Problem 11CTQ
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QUESTION 7
Copy the figure shown below onto your scratch paper.
Box 1
Box 2
Box 3
HBr
Br
Then, complete the figure on your scratch paper by drawing out the intermediates and arrow-pushing mechanism in Boxes 1-3 that explain the formation of the final products shown. You should start your arrow-pushing in Box
1, and you will use all boxes.
Now, report the formal charges (+,0,-) that appear on the alpha carbon, beta carbon, and bromine atoms in each box, and match the contents of each box to a single phrase (A-H) that best describes the mechanistic step that
Occurs in each box.
A. A hydride shift occurs.
B. A methyl shift occurs.
C. A nucleophile attacks a tertiary carbocation.
D. A leaving group leaves.
E. A nucleophile attacks a secondary carbocation.
F. Br is protonated, the alpha carbon is deprotonated, and a pi bond forms
G. A carbocation attacks the Br.
H. Br is protonated, the beta carbon is deprotonated, and a pi bond forms
Ca formal charge (+,0,-) CR formal charge (+,0,-) Br formal charge (+,0,-) Phrase (A-H)
主
Вох 1: 0
Воx 2:
Вох 3:
Products: 0
0.
Transcribed Image Text:QUESTION 7 Copy the figure shown below onto your scratch paper. Box 1 Box 2 Box 3 HBr Br Then, complete the figure on your scratch paper by drawing out the intermediates and arrow-pushing mechanism in Boxes 1-3 that explain the formation of the final products shown. You should start your arrow-pushing in Box 1, and you will use all boxes. Now, report the formal charges (+,0,-) that appear on the alpha carbon, beta carbon, and bromine atoms in each box, and match the contents of each box to a single phrase (A-H) that best describes the mechanistic step that Occurs in each box. A. A hydride shift occurs. B. A methyl shift occurs. C. A nucleophile attacks a tertiary carbocation. D. A leaving group leaves. E. A nucleophile attacks a secondary carbocation. F. Br is protonated, the alpha carbon is deprotonated, and a pi bond forms G. A carbocation attacks the Br. H. Br is protonated, the beta carbon is deprotonated, and a pi bond forms Ca formal charge (+,0,-) CR formal charge (+,0,-) Br formal charge (+,0,-) Phrase (A-H) 主 Вох 1: 0 Воx 2: Вох 3: Products: 0 0.
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