Cyclohexane derivatives exist primarily in the most stable of the available chair conformations. Give the position, axial or equatorial, of each of the three groups shown when the ring is in the most stable chair conformation. If a group divides its time equally between axial and equatorial positions, indicate this with ax/eq. The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for answering this question. CO2H a "CH3 Group a is Group b is Group c is

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter2: Alkanes And Cycloalkanes
Section: Chapter Questions
Problem 2.45P: Gibbs free energy differences between axial-substituted and equatorial-substituted chair...
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Give the position, axial or equatorial, of each of the three groups shown when the ring is in the most stable chair conformation

Indicate whether the pair of structures shown represent stereoisomers, constitutional isomers, different conformations of the same
compound, or the same conformation of a compound viewed from a different perspective.
Note that cis, trans isomers are an example of stereoisomers.
OCH3
CH30-
CH30.
LOCH3
H3C.
H3C-
CH3
ČH3
Transcribed Image Text:Indicate whether the pair of structures shown represent stereoisomers, constitutional isomers, different conformations of the same compound, or the same conformation of a compound viewed from a different perspective. Note that cis, trans isomers are an example of stereoisomers. OCH3 CH30- CH30. LOCH3 H3C. H3C- CH3 ČH3
Cyclohexane derivatives exist primarily in the most stable of the available chair conformations. Give the position, axial or equatorial, of
each of the three groups shown when the ring is in the most stable chair conformation. If a group divides its time equally between axial
and equatorial positions, indicate this with ax/eq.
The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference
tool is useful for answering this question.
CO2H
a
"CH3
Group a is
Group b is
Group c is
Transcribed Image Text:Cyclohexane derivatives exist primarily in the most stable of the available chair conformations. Give the position, axial or equatorial, of each of the three groups shown when the ring is in the most stable chair conformation. If a group divides its time equally between axial and equatorial positions, indicate this with ax/eq. The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for answering this question. CO2H a "CH3 Group a is Group b is Group c is
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