(d) Determine the structure of the product or the reaction conditions in the following transformations; provide a curved arrow mechanism for each transformation: MnO₂ H OH OH Acetone 1) Os, MeOH 2) Me₂S 1) LDA then PhSeBr 2) H₂O₂ OH

(d) Determine the structure of the product or the reaction conditions in the following transformations; provide a curved arrow mechanism for each transformation: MnO₂ H OH OH Acetone 1) Os, MeOH 2) Me₂S 1) LDA then PhSeBr 2) H₂O₂ OH

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions

Section30.SE: Something Extra

Problem 27AP

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Concept explainers

Aldehydes and Ketones

Aldehydes and ketones are organic compounds that have a carbonyl group, C = O, as their functional group. They both differ in the placement of this carbonyl group in their structures.

Question

(d) Determine the structure of the product or the reaction conditions in the following
transformations; provide a curved arrow mechanism for each transformation:
MnO₂
Acetone
OH
OH
1) O3, MeOH
2) Me₂S
1) LDA then PhSeBr
2) H₂O₂
?
Q:
OH

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