d) For each of the following pairs of structures, circle the stronger Brønsted acid. H´ `OCH3 `NH2 `OCH3 CH;OH2 CH;NH3 H H;C-CEÑ-H H;C `OCH3 OCH3 H e) 1,3,5-heptatriene (1) reacts with HBr at very low temperature to give a cation intermediate, which leads one major product. This product is obtained under both kinetic and thermodynamic conditions. Give the structure of the product, and draw the three most important resonance contributors to the structure of the cat intermediate. HBr C,H„Br Cation Intermediate

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d) For each of the following pairs of structures, circle the stronger Brønsted acid.
„H
`OCH3
`NH2
`OCH3
CH;OH2
CH;NH3
H
HạC-CEN-H
H3C
`OCH3
`OCH3
e) 1,3,5-heptatriene (1) reacts with HBr at very low temperature to give a cation intermediate, which leads to
one major product. This product is obtained under both kinetic and thermodynamic conditions. Give the
structure of the product, and draw the three most important resonance contributors to the structure of the cation
intermediate.
HBr
C,H1,Br
Cation
Intermediate
Oz-I
Transcribed Image Text:d) For each of the following pairs of structures, circle the stronger Brønsted acid. „H `OCH3 `NH2 `OCH3 CH;OH2 CH;NH3 H HạC-CEN-H H3C `OCH3 `OCH3 e) 1,3,5-heptatriene (1) reacts with HBr at very low temperature to give a cation intermediate, which leads to one major product. This product is obtained under both kinetic and thermodynamic conditions. Give the structure of the product, and draw the three most important resonance contributors to the structure of the cation intermediate. HBr C,H1,Br Cation Intermediate Oz-I
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