Deduce the IR and Raman active carbonyl vibrations for both the cisand trans isomers of L2M(CO)4 and Fe(CO)4CI has IR bands at 2167,2126 and 1082 cm in CHCI3 solution. How would you interpret thisspectrum and identify the isomer?

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Answered: Deduce the IR and Raman active carbonyl…

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter14: Rotational And Vibrational Spectroscopy

Section: Chapter Questions

Problem 14.85E

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Deduce the IR and Raman active carbonyl vibrations for both the cis and trans isomers of L2M(CO)4 and Fe(CO)4Cl has IR bands at 2167, 2126 and 1082 cm in CHCI3 solution. How would you interpret this spectrum and identify the isomer?