1.What are the ground free ion term and ground J state for gas phase  neodymium in the  plus three oxidation state (Nd3+(g))  ? 2.Why do the effective magnetic moments at 300K  for first d-transition  series metal ions in the gas phase fit best for the small multiplet splitting limit , but lanthanide  species have effective magnetic moments at 300K that are well fitted by the limiting large multiplet splitting  ?

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter10: Atomic Emission Spectrometry
Section: Chapter Questions
Problem 10.8QAP
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1.What are the ground free ion term and ground J state for gas phase  neodymium in the  plus three oxidation state (Nd3+(g))  ?

2.Why do the effective magnetic moments at 300K  for first d-transition  series metal ions in the gas phase fit best for the small multiplet splitting limit , but lanthanide  species have effective magnetic moments at 300K that are well fitted by the limiting large multiplet splitting  ?

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