Derive the integrated form of a third-order rate law v = kr[A]2[B] in which the stoichiometry is 2 A + B → P and the reactants are initially present in (a) their stoichiometric proportions ([B]0 = 12[A]0); (b) with B present initially in twice that amount ([B]0 = [A]0). Express your rate law in terms of [A]0, [B]0, and x, where [A] = [A]0 − 2x.
Derive the integrated form of a third-order rate law v = kr[A]2[B] in which the stoichiometry is 2 A + B → P and the reactants are initially present in (a) their stoichiometric proportions ([B]0 = 12[A]0); (b) with B present initially in twice that amount ([B]0 = [A]0). Express your rate law in terms of [A]0, [B]0, and x, where [A] = [A]0 − 2x.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 25QRT
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Derive the integrated form of a third-order rate law v = kr[A]2[B] in which the stoichiometry is 2 A + B → P and the reactants are initially present in (a) their stoichiometric proportions ([B]0 = 12[A]0); (b) with B present initially in twice that amount ([B]0 = [A]0). Express your rate law in terms of [A]0, [B]0, and x, where [A] = [A]0 − 2x.
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