Describe the formation of metal complex with octahedral geometry using all the orbitals of same energy level. Illustrate (with any one example) magnetic properties with justification. Give details of atomic number, electronic configuration, hybridization, with structure of the complex.

Describe the formation of metal complex with octahedral geometry using all the orbitals of same energy level. Illustrate (with any one example) magnetic properties with justification. Give details of atomic number, electronic configuration, hybridization, with structure of the complex.

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 70AP

See similar textbooks

Related questions

Q: Identify the oxidizing agent in the following chemical reaction. Cu2+(aq) + Fe(s) → Cu(s) ...

Q: Calculate the kinetic energy of a 0.16 kg baseball moving at a speed of 25.0 Round your answer to 2 ...

A: Given that, the mass of a baseball is m = 0.16 kg. The speed of the it is v = 25.0 m/s. We have to c...

Q: Your answer is correct. Given reaction A+ 2B→ 3C+ 4 D with following standard enthalpies of formatio...

A: Given, A + 2B ➝ 3C + 4D Species standard enthalpy of formation A 10...

Q: work done on the gas mixture. Be sure your answer has the correct sign (positive or negative) and th...

Q: Green plants use light from the Sun to drive photosynthesis. Photosynthesis is a chemical reaction i...

Q: Determine the ionic strength, 4, for each of the solutions. Assume complete dissociation of cach sal...

A: The ionic strength can be calculated as follows

Q: A. Sucralose, an artificial sweetener comen used by diabetic patients, II. Solve the following probl...

A: Compute the number of moles of chlorine in 102.4 g of sucralose. Mass of sucralose = 102.4 g Molecu...

Q: What is the nickel ion concentration in a solution prepared by mixing 381 mL of 0.395 M nickel nitra...

Q: For the exothermic reaction, name three ways you could increase the amount of O2 in the container wi...

Q: 1point You got a new lego set on your birthday and you build an air plane. The change in the entropy...

A: 3 1 pont You got a new lego set on your birthday and you build an air plane. The change in the entro...

Q: 1.27 x10-36) in each liquid or solution Determine the molar solubility of CuS (Ksp provided below: i...

A: We have to find the molar solubility of CuS in pure water and 0.25M CuCl2 Ksp of CuS = 1.27×10-36

Q: Which of the following items is a chemical property? the melting and boiling point of water ...

A: Given:- Which of the following items is a chemical property? the melting and boiling point...

Q: How would you prepare x 10 ^2 mL of 0.9 M NaOH solution, starting from 5.01 M stock solution? (give...

A: Given that, M1=5.01 M, V1=? M2=0.9 M , V2= 2×102 ml = 200 ml then,

Q: Show your solutions n1= 5.38mol V1= 89.3L V2= 92.3L Find n2

A: Given that, n1 = 5.38 mol, V1 = 89.3 L, V2 = 92.3 L, n2 = ? According to Avogadro's law, the volu...

Q: Acids and bases are among the most common and important compounds known. Discuss an application of ...

A: I will give you applications for acid and bases

Q: 1. Write down the structures of A and B, the mechanisms of all transformations and explain the stere...

Q: pKa of NH4* = 7.2 MW of NH,CI = 53.49 g/mol Adding 4.01 g of NH4CI(s) to a 1.0 L solution of 0.075 M...

Q: Wayne needs 10.87 moles of ammonium nitrate, NH4NO3, for an experiment. How many grams will he need ...

A: A question based on mole concept that is to be accomplished.

Q: Sulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid...

Q: Question 2: Explain the 'H-NMR spectrum generated for 1,3-dichloropropane would differ compared to t...

A: We have to compare the 1H NMR spectrum of 1,3-dichloropropane and 1,2-dichloropropane.

Q: A 150.0 gram sample of a white powder contains 61.05 g of carbon, 7.65 g of hydrogen, and 81.30 g of...

Q: In a chemical reaction, the substances present after the chemical change are called reactants. True...

A: In a chemical reaction Reactants are substances that start a chemical reaction. Products are substan...

Q: In the UV assay of paracetamol you are required to weigh tablet powder “…containing 0.150 g of Parac...

A: Answer : weight of 1 tablet = mass of tablet / no. of tablet = 11.223/20 = 0.56115 g as 1 mg = 0....

Q: 1. Identify the functional groups in each compound. Some compounds contain more than one functional ...

A: Since you have posted multiple questions, we'll answer the first one. If you want any other question...

Q: Data Table 1: Gas volumes observed at 15 minutes Interval Sugar Initial 15 30 45 60 Total Glucose 0....

A: In presence of oxygen gas, glucose is converted into CO2 and water. In this process, 38 ATPs are gen...

Q: Measurements show that the energy of a mixture of gaseous reactants decreases by 174. kJ during a ce...

A: Energy of a mixture of gaseous reactants decreases by 174. kJ Therefore, ∆U = - 174. kJ Work done...

Q: What is the identity of the gas that forms when vinegar is added to baking powder?

Q: thermometer A 52.4 g sample of brass is put into a calorimeter (see sketch at right) that contains 3...

A: Given value, For brass, m=52.4 g, T1=90.0℃ , T2=17.3 ℃ Specific heat capacity of brass (Cp) =?

Q: 4. A system receives 75 J of electrical work, delivers 274 J of expansion work, and absorbs 168 J of...

A: Givens : Work done by the system , W = 274 joules Heat absorbed by the...

Q: Consider the combustion reaction of a 1.0 mol C3H1005-an organic compound, in an open atmosphere (co...

A: We know That ∆H=∆U+∆ngRT

Q: . What is the pH of a 0.202 M aqueous solution of sodium acetate, NaCH3COO? pH = The solution is ...

A: sodium acetate, CH3COONa is a salt of a weak acid (CH3COOH) and strong base (NaOH). given, the conce...

Q: 1. What is the color result for red and blue litmus paper when exposed to the fume of heated albumin...

A: Since you have asked multiple question, we will solve the first question for you.If you want any spe...

Q: If a pure material decomposes when heated into simpler substances, this proves that the material was...

Q: thermometer. .6 g sample of iron, which has a specific heat capacity of 0.449 J-g .°c, is put into a...

Q: 1. Solutions of known % (v/v) is prepared by the use of . a. balance b. volumetric flask c. graduate...

Q: Wine goes bad soon after opening because the ethanol (CH,CH,OH) in it reacts with oxygen gas (0,) fr...

A: CH3CH2OH + O2 CH3CH2OH + H2O 1 mole of ethanol reacts with 1 mole of oxygen to form 1 mole of ...

Q: Mercury is an environmental pollutant because it can be converted by certain bacteria into the very ...

A: This problem is solved by the unitary method. Given mass of mercury is 241 tons and 1.9% of this amo...

Q: If a 14.0 g chunk of gold at 20.0°C is dropped into 25.0 g of water at 80.0 °C, what is the final te...

A: Given, For Gold: Mass of gold (mGold) = 14.0 g Note: Specific heat capacity of gold (CpGold) = 0.129...

Q: A mixture of gaseous reactants is put into a cylinder, where a chemical reaction turns them into gas...

A: A numerical problem based on thermodynamics that is to be accomplished.

Q: 1. What is the chemical reaction involved i the synthesis of methyl salicylate? 2. Give also the re...

Q: dm3 to 10.0dm3 at 500°C. Calculate the work done assuming a. The gas to be ideal a = 5.536 dm3 bar /...

Q: Gaseous ethane (CH,CH;) reacts with gaseous oxygen gas (02) to produce gaseous carbon dioxide (CO2) ...

A: Reaction between ethane and oxygen (Combustion of ethane) 2C2H6 (g...

Q: You need to make 100 mL of a 2.5% dextrose solution for a hypoglycemic kitten using the 50% stock so...

A: Given that, V1=100 ml, %solution of 1=2.5 % V2= ? , % solution of 2 =50%

Q: Derive simplified expressions for F? or diamond, including the rules governing observed reflections....

A: Given:-

Q: 11. It has been determined that the body can generate 5500 kJ of energy during one hour of strenuous...

A: Energy generated during one hour exercise = 5500kJ Heat of vaporization of water = 40.6kJ/mol Time o...

Q: Convert 0.19 moles of carbon dioxide to grams of CO2.

A: Answer: This is question based on mole concept where each mole of the substance has a fixed mass cal...

Q: Tooling for a vacuum deposition system is cleaned and reassembled. Unfortunately, a drop of water 0....

A: Given that, a drop of water has a volume is 0.125 cm3. The pressure of the chamber is P = 4.3×10-6 t...

Q: thermometer A 56.0 g sample of iron, which has a specific heat capacity of 0.449 Jg.C, is put into a...

A: We have to use the principle of calorimetry which says hear given = heat absorbed. We know q=mC∆T w...

Q: Is the following solution a buffer? Each solution was prepared by mixing and diluting appropriate qu...

A: An acid is a substance that give hydrogen ions in solution and a base is a substance that give hydro...

Q: The following initial rate data are for the gas phase reaction of hydrogen with iodine: H2 + I2 → 2 ...

Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

A. Describe the formation of metal complex with octahedral geometry using all the orbitals of
same energy level. Illustrate (with any one example) magnetic properties with justification.
Give details of atomic number, electronic configuration, hybridization, with structure of the
complex.
B. Explain the role of biological system that produce fruits by natural process.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step 5

Step 6

Step 7

Step 8

Step by step

Solved in 8 steps with 5 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Draw the appropriate completely Orgel Diagram and use it to assign elctronic transition/s to any of these bands , confirming the colour of the complex
Write the examples of Bidentate and Polydentate ligands? Also distinguish them.
The stability of metal complexes with EDTA is due to the formation of?A) ZwitterionB) Chelate complexC) Azo dyeD) Quinoid structureE) Arylmethane dye
Find out that how a complex with the empirical formula given in below can attain an 18 electron configuration?Give c
Divide the electron configurations d1 through d10 among the groupmembers such that every configuration is assigned to at least twogroup members. Working individually, draw the orbital diagram forthe configurations assigned to you, including both high-spin andlow-spin diagrams where possible. Present your diagrams to yourgroup. Combine all diagrams into one set for the group.
The two egorbitals are identical in energy in an octahedralcomplex but have different energies in a square planar complex,with the dz2orbital being much lower in energy than the dx2-y2 .Explain with orbital sketches.
Regarding the formation of the tetracyanetoniquelate (II) complex answer:a.Demonstrates hybridization according to the valence bond theory and indicate itsgeometry.b. Demonstrate and explain the unfolding of the crystalline field in the formation of this ioncomplex.c. Demonstrate through a diagram of molecular orbitals and explain the formation of that ioncomplex according to the ligand field theory
Mention Any Five Uses Of The Coordination Compounds In Industrial in sector of file?
(a) Using Werner’s definition of valence, which property isthe same as oxidation number, primary valence or secondaryvalence? (b) What term do we normally use for the othertype of valence? (c) Why can NH3 serve as a ligand but BH3cannot?
Among the (pi) acid ligands of groups 15 and 16, which is the most similar, regarding the capacity ofretro-donation, to the CO? Why?
Compare the two complexes attached in the picture through the result of the mutual influence of π between them, explaining the reason
Work out the stoichiometries and structures of the neutral complexes, chromium carbonyl, rhenium carbonyl, and nickel carbonyl using the 18-electron rule. Then use valence bond theory to determine the hybridizations of the orbitals in each complex?