Describe the procedure of Lewis structures for polyatomic ions?

World of Chemistry, 3rd edition
3rd Edition
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Chapter12: Chemical Bonding
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Describe the procedure of Lewis structures for polyatomic ions?

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Step 1

Lewis structure of a molecule is the representation to show the valence electrons along with the bonds around atoms of the molecule. Bonds are represented by line while the electrons are represented as dots around the atoms. Octet of all atoms are fulfilled except hydrogen.

Step 2

Steps followed to consider the draw the Lewis structure for polyatomic ion is as follows:

 

Consider the example of ammonium ionNH4+ to understand the procedure to determine the Lewis structure.

In step 1, calculate the total valence electrons on the polyatomic ion. Total valence electrons is the sum of valence electrons of each element multiplied by the number of that element present in the compound. In case of polyatomic ions, the number of negative charges is added to the total valence electron and the number of positive charges is subtracted from the total valence electron.

 

Each nitrogen atom has five valence electrons and the hydrogen atom has one valence electron. Subtract one electron due to the presence of +1 charge.

Total Valence Electrons=Valence ElectronsN+4Valence ElectronsH-1=5+41-1=8

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