Determine the differences in pH when a strong base is used to titrate a strong acid and a weak acid. Consider the following reactions: HC1 + NaOH, (aq) → NaCl (aq) + H2O (1 (ад) HC;H;O2 (ag) + NaOH (ag) → NaC:H;O2 (a) + H2O (1) Experiment 1: 0.2773 M NaOH is used to titrate 10.00 mL of 0.7198 M HC1 Experiment 2: 0.2773 M NaOH is used to titrate 10.00 mL of 0.7198 M HC:H;O2 (K. = 1.75 x 10) Because the volumes and concentrations are the same for both titrations, the volume of titrant required to reach the equivalence point is also the same: 25.96 mL of NaOH. Calculate the following: 1. The pH of both acids before any base has been added (initial pH). 2. The pH at the equivalence point for the HC,H;O2 + NaOH titration. 3. The pH when 25.00 mL has been added in the HCl + NaOH titration 4. The pH when 8.00 mL has been added in the HC.H;O2 + NaOH titration,

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter16: Reactions Between Acids And Bases
Section: Chapter Questions
Problem 16.26QE
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Determine the differences in pH when a strong base is used to titrate a strong acid and a weak
acid. Consider the following reactions:
HC1
(ад)
+ NaOH
(aq)
→ NaCl
+ H2O a
(ад)
HC;H;O2 (aq) + NaOH
→ NaCH;O2 (ag) + H2O )
(аq)
Experiment 1:
0.2773 M NaOH is used to titrate 10.00 mL of 0.7198 M HC1
Experiment 2:
0.2773 M NaOH is used to titrate 10.00 mL of 0.7198 M HC:H;O2 (K. = 1.75 x 10*)
Because the volumes and concentrations are the same for both titrations, the volume of titrant
required to reach the equivalence point is also the same: 25.96 mL of NaOH.
Calculate the following:
1. The pH of both acids before any base has been added (initial pH).
2. The pH at the equivalence point for the HCH;O2 + NaOH titration.
3. The pH when 25.00 mL has been added in the HCl + NaOH titration
4. The pH when 8.00 mL has been added in the HC:H;O2 + NaOH titration,
Transcribed Image Text:Determine the differences in pH when a strong base is used to titrate a strong acid and a weak acid. Consider the following reactions: HC1 (ад) + NaOH (aq) → NaCl + H2O a (ад) HC;H;O2 (aq) + NaOH → NaCH;O2 (ag) + H2O ) (аq) Experiment 1: 0.2773 M NaOH is used to titrate 10.00 mL of 0.7198 M HC1 Experiment 2: 0.2773 M NaOH is used to titrate 10.00 mL of 0.7198 M HC:H;O2 (K. = 1.75 x 10*) Because the volumes and concentrations are the same for both titrations, the volume of titrant required to reach the equivalence point is also the same: 25.96 mL of NaOH. Calculate the following: 1. The pH of both acids before any base has been added (initial pH). 2. The pH at the equivalence point for the HCH;O2 + NaOH titration. 3. The pH when 25.00 mL has been added in the HCl + NaOH titration 4. The pH when 8.00 mL has been added in the HC:H;O2 + NaOH titration,
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