Determine the electronic configuration (in the form t2g "eg or emt2" , as appropriate) and the ligand field stabilization energy for each of the following complexes (1)[Co(NH3)6] 3* ; (II) [Fe(OH2)6] 2+

Q: 7) If you were to use a ligand L that was a stronger field ligand than NH3, what color would you…

A: Step : 1             The required answer is follows as :

Q: Why can NH3 serve as a ligand but BH3 cannot?

A:

Q: The oxalate ligand, [C:O4]²*, is a bidentate ligand and the structure of a complex ion [Fe(ox);]² is…

A: The given complex ion is a coordination complex with central metal ion (Fe3+) having 6-coordinate…

Q: For the coordination compound K2[Co(H2O)2Cl½Brz] a) Give the name of the compound and oxidation…

A: a) Name of compound- potassium diaquadibromodichlorocobaltate(II) oxidation state of metal - +2   b)…

Q: Subsequently, derive the p-bonding ligand group orbitals and draw a second qualitative molecular…

A: P- Bonding in ligand group orbital- we will discuss p-bonding in ligand by taking some eexamples-…

Q: Ligand A, B, and C form complexes with a metal cation resulting to  violet, indigo, and blue aqueous…

A:

Q: The metal ion, M2+, formed a paramagnetic tetrahedral complex [MJ4]2+, having three unpaired…

A: Given: We have to calculate the hybridization of given M2+ ion.

Q: the complex [CrO7]² is bright orange colored, suggest reason for that ?

A: In this question, we will discuss about why complex [Cr2O7]2- ion is bright orange color.  You can…

Q: What is the nature of the orbitals involved in the Alq3, from both the metal center and the ligands…

A: The given structure is,

Q: Consider the following metal ion d-electron configuration and crystal field in octahedral complexes:…

A: Crystal Field Stabilizing Energy (CFSE),in terms of ∆° and P:   CFSE =[-0.4 p+0.6 q ] ∆° +m Pwhere,p…

Q: 12. Sketch the d-orbital energy levels for the following molecular geometries: ligand environment…

A:

Q: The octahedral ion complex [CoF6] 3‒ absorbs at 675 nm. (a) What color is the complex? (b)…

A:

Q: By using valence bond theory and ligand field theory, prove that [Ru(OMe)2(PMe3)4] is a paramagnetic…

A:

Q: Explain the stability of the complexes TiCl62- and [Zn(en)3]2+

A: TiCl62-  is less stable than [Zn(en)3]+2 because Ethylene Di ammine is bidentate ligand so it will…

Q: Show how the coordination of two MeHNCH2CH2NH2 ligands to a metal atom in a square planar complex…

A: Optical isomers: Two compound having same molecular formula but different in spatial arrangement…

Q: F3C-M ligand is a pi acceptor/ pi donor or neither?

A: pi acceptor ligands are those in which it have empty p orbitals and a good sigma donor. When bonding…

Q: 2) draw the MO diagrams to show the effect of pi-back bonding in the square planar metal complexes…

A: THE SOLUTION IS SHOWN BELOW.

Q: 4. The structure of [Cu(NH3)4]²+ is known to be square planar. Using the ligand o orbitals only,…

A: Given that  Square planer metal complex [Cu(NH3)4]2+ (ML4) Draw orbitals symmetries of the central…

Q: Take the following complexes into account: A)[Co(en);]I3 B) Liq[COF3(OH)3] a) Which type of…

A: Hello. Since your question has multiple sub-parts, we will solve the first three sub-parts for you.…

Q: Define the ambidentate ligand and give two examples.

A: Those ligand which can donate electrons from two different atom site but donate from 1 site at one…

Q: How many stereoisomers exist for octahedrally shaped complex MA4(en), assuming A is monodentate…

A:

Q: Calculate the Ligand-field stabilization energies (LFSE) for octahedral compounds which contain the…

A: The high spin complexes contain the unpaired electrons whereas the low spin complexes contain the…

Q: Give an example of ambidentate ligand.

A: Ligands containing two or more donor atoms but only one coordinates with metal atom to give complex…

Q: By taking into account the following complexes: A) [Co(en):]³* B)[CoCl3Br3]+ a) Give the oxidation…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: An octahedral complex, MA,B2C2 (A, B, C are all monodentate ligands), has a total of 6…

A: The correct option is as follows:

Q: The metal ion, M2+, formed a paramagnetic tetrahedral complex [MJ4]2+, having three unpaired…

A: The given metal ion is M2+

Q: Why can the NH3 molecule serve as a ligand but the BH3 molecule cannot?

A: A ligand is an atom or group of atoms which is linked to a central metal atom or ion in a complex…

Q: Explain why, for the same metallic cation and the same ligands, the energy of the binding field is…

A: The question is based on the concept of coordination chemistry. We have to explain the low binding…

Q: Mo(PMes)3(C6HS)2

A:

Q: Which orbital is LUMO in the molecular orbital diagram drawn for the sigma interaction of the…

A: As there is six mano dented ligands are there . Thus it is octahedral complex.  Where every mano…

Q: Pyridine (C5H5N), abbreviated py, Would you expect pyridine to act as a monodentate or bidentate…

A: Ligands are electron rich species. The electrons are donated to the central metal atom. The given…

Q: The factor determining the mechanism observed in the substitution reactions of square plane…

A: here, for the nucleophilic substitution reaction Sn2 for the inorganic reaction mechanism  yes, This…

Q: Explain the following terms giving a suitable example in each case :(i) Ambident ligand(ii)…

A: Following terms are explained below-

Q: The two egorbitals are identical in energy in an octahedralcomplex but have different energies in a…

A: The ligands are electron donors and they can donate the unshared electron pairs to the electrophilic…

Q: For the hexacyanoferrate(III) ion, [Fe(CN)6]^3- calculate the crystal field stabilization energy…

A: Given : We have to calculate the CFSE for [Fe(CN)6]3- .

Q: explain and prove if [Fe(acac)3] is diamagnetic high spin octahedral complex using valence bond…

A: Acac is strong feild ligand, so according to VBT pairing take place and formation inner sphere…

Q: Suppose that you want to determine whether a ligand X is a weak-field or strong-field ligand. Would…

A: Strong field ligand are able to pair the electrons while weak field ligand are not able to pair…

Q: Write the examples of Bidentate and Polydentate ligands? Also distinguish them.

A: Ligands can be described as an anions or cations or neutral molecules which is further classified as…

Q: Are bipyridines (bipy) and analogous amines, phenanthroline (phen) and terpyridine (terpy) chelate…

A: Yes, bipyridine and analogous amines, phenanthroline and terpyridine are chelate ligands.

Q: According to the theory of molecular orbitals, how are ligands classified and what effect do they…

A: On the basis of molecular orbital Theory , ligands are classified into :  1.) Only sigma donor 2.)…

Q: iv. Compound 2 has a distorted octahedral geometry, with four short and two longer Co-P bond…

A: The Phosphine ligand is a strong field ligand than "en" ligand because in phosphine ligand contains…

Q: Calculate the ligand field stabilization energy, electron pairing energy (N and N) and spin-only…

A: The given compound, [Ni(NH3)6]Cl3 is an octahedral complex, here, 6 NH3 ligands are present. This…

Q: The complex Mo(CO)3(NCC2H5)3 has the infrared spectrum shown below. Is this complex more likely the…

A: The mentioned complex is Mo(CO)3(NCC2H5)3

Q: For each of the following complexe ate) and give its magnetic propertie 3. [Fe(NH,),J²* [Cr(CO),J*

A: Concept is based on spectrochemical series. It decides the spin of ligands.

Q: The DOTA ligand is a cyclic octadentate ligand with four N- donors and four O-donors. * True O False

A:

Q: Which of the following ligands is bidentate?

A: Edta , diene and triene have more than 2 donor sites.