Determine the point group of each of the following molecules or ions, whose shapes can be determined by use of valence-shell electron-pair repulsion (VSEPR) theory: (a) SeF5. (b) CIF, (c) AsF. (d) XeF₂, (e) XeF₁. (f) BeF3. (g) SiF2, (h) OCN, (i) ASCI, () OSF4, (k) trans-FNNF, (1) cis-FNNF, (m) CISSCI (nonplanar), (n) S₂O3, (o) trans-(OH)4XeO₂.
Determine the point group of each of the following molecules or ions, whose shapes can be determined by use of valence-shell electron-pair repulsion (VSEPR) theory: (a) SeF5. (b) CIF, (c) AsF. (d) XeF₂, (e) XeF₁. (f) BeF3. (g) SiF2, (h) OCN, (i) ASCI, () OSF4, (k) trans-FNNF, (1) cis-FNNF, (m) CISSCI (nonplanar), (n) S₂O3, (o) trans-(OH)4XeO₂.
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter13: Introduction To Symmetry In Quantum Mechanics
Section: Chapter Questions
Problem 13.29E: Determine the point groups of the following molecules. a Fe(CO)5, which has a trigonal bipyramidal...
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![Determine the point group of each of the following molecules or ions, whose
shapes can be determined by use of valence-shell electron-pair repulsion.
(VSEPR) theory: (a) SeF5. (b) CIF, (c) ASF, (d) XeF₂, (e) XeF4. (f) BeF3.
(g) SiF2, (h) OCN, (i) ASCI, (j) OSF4, (k) trans-FNNF, (1) cis-FNNF, (m)
CISSCI (nonplanar), (n) S₂O3, (o) trans-(OH)4XeO₂.
ww
Identify the point group for each of the following Fe³+ complexes with the biden-
tate oxalate ligand (ox = C₂O2). Where allowed by the point group, determine
which complexes are chiral. [Hint: Use models to help identify the point group
and to verify the existence of enantiomers.]
(a) tris(oxalato)ferrate(III), [Fe(ox);]³
(b) trans-dichlorobis(oxalato)ferrate(III). [FeCl₂(ox)₂³
(c) cis-dichlorobis(oxalato)ferrate(III), [FeCl₂(ox)₂]
(d) cis-dibromo-trans-dichlorooxalatoferrate (III). [FeBr₂Cl₂ox]³
(e) cis-dibromodichlorooxalatoferrate(III), [FeBr₂Cl₂ox]³.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff081d80d-7bd1-4f36-a4b3-96dbdf50571e%2Fbebedaa1-18c8-4aab-b46c-6a4b1f1ac203%2Fi1ebukj_processed.png&w=3840&q=75)
Transcribed Image Text:Determine the point group of each of the following molecules or ions, whose
shapes can be determined by use of valence-shell electron-pair repulsion.
(VSEPR) theory: (a) SeF5. (b) CIF, (c) ASF, (d) XeF₂, (e) XeF4. (f) BeF3.
(g) SiF2, (h) OCN, (i) ASCI, (j) OSF4, (k) trans-FNNF, (1) cis-FNNF, (m)
CISSCI (nonplanar), (n) S₂O3, (o) trans-(OH)4XeO₂.
ww
Identify the point group for each of the following Fe³+ complexes with the biden-
tate oxalate ligand (ox = C₂O2). Where allowed by the point group, determine
which complexes are chiral. [Hint: Use models to help identify the point group
and to verify the existence of enantiomers.]
(a) tris(oxalato)ferrate(III), [Fe(ox);]³
(b) trans-dichlorobis(oxalato)ferrate(III). [FeCl₂(ox)₂³
(c) cis-dichlorobis(oxalato)ferrate(III), [FeCl₂(ox)₂]
(d) cis-dibromo-trans-dichlorooxalatoferrate (III). [FeBr₂Cl₂ox]³
(e) cis-dibromodichlorooxalatoferrate(III), [FeBr₂Cl₂ox]³.
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