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Determine the point groups for Chloroethylene.
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- Structural isomers can have very different point groups. There are three isomers of dichlorobenzene. Identify the point groups of the three isomers.Determine the point group of the following molecules. a cis1,2 Dichloroethylene b trans1,2 Dichloroethylene c Toluene, C6H5CH3 d 1,3-Cyclohexadiene.Determine the point groups of the following molecules. a Fe(CO)5, which has a trigonal bipyramidal structure, b CO32, which has three resonance structures that contribute to its overall shape, c The perfectly staggered conformation of ethane, d The perfectly eclipsed conformer of ethane.
- Structural isomers can have very different point groups. Determine the point groups of 1,4cyclohexadiene and 1,3cyclohexadiene, which both have the molecular formula C6H8.Determine which single symmetry operation of the following point groups is equivalent to the given combination of multiple symmetry operations. a In C2v, C2v=? b In C2h, iC2=? c In D6h, C6h=? d In D2d, C2C2=? e In Oh, iS4=?Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.
- What are the number of classes and the order of the following point groups? a C2v b D2h c D6h d S4 e Cs.Determine the point groups of the following molecules. a Hydrogen selenide, H2Se b Partially deuterated hydrogen sulfide, or HDS c The chair conformer of cyclohexane, C6H12 d The boat conformer of cyclohexane, C6H12Show that any two of the irreducible representations of the following point groups are orthogonal to each other. a C2 b C2v c D2h d Oh e Td
- Show that any irreducible representation of these point groups is normalized. a C2 b D2d c Oh d C4h e C6vDetermine the symmetry species of the D3h point group for the sp2 hybrid orbitals, assuming that the C3 axis is coincident with the z-axis and that one of the orbitals lies along the positive x-axis. See Example 13.16.Why is it unnecessary to consider whether an irreducible representation from C4h is orthogonal to an irreducible representation of D6h?