Determine the rate law for the production of nitrosyl fluoride (NO2F) that occurs according to the following balanced chemical equation: 2 NO2 (g) + F2 (g) → 2 NO2F (g) The following data were obtained from varying the concentrations of the reactants: [NO2] (M) [F2] (M) Initial Rate (M/s) Run 1 0.00130 0.00479 2.16 x 104 Run 2 0.00259 0.00479 4.30 x 10-4 Run 3 0.00612 0.00123 2.61 x 104 Run 4 0.00612 0.00246 5.22 x 10-4 CA) B) C) D) CE) Rate = k [NO2] [F2] Rate = k [NO2]²[F2] Rate = k [NO2] Rate = k [NO2]?[F2]0.5 Rate = k [NO2] [F2]0.5

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.42QE
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Determine the rate law for the production of nitrosyl fluoride (NO2F) that occurs according to the following
balanced chemical equation:
2 NO2 (g) + F2 (g) → 2 NO2F (g)
The following data were obtained from varying the concentrations of the reactants:
[NO2] (M)
[F2] (M)
Initial Rate (M/s)
Run 1
0.00130
0.00479
2.16 x 104
Run 2
0.00259
0.00479
4.30 x 10-4
Run 3
0.00612
0.00123
2.61 x 104
Run 4
0.00612
0.00246
5.22 x 104
(A)
(B)
(C)
(D)
(E)
Rate = k [NO2] [F2]
Rate = k [NO2]?[F2]
Rate = k [NO2]
Rate = k [NO2]?[F2]0.5
Rate = k [NO2] [F2]0.5
Transcribed Image Text:Determine the rate law for the production of nitrosyl fluoride (NO2F) that occurs according to the following balanced chemical equation: 2 NO2 (g) + F2 (g) → 2 NO2F (g) The following data were obtained from varying the concentrations of the reactants: [NO2] (M) [F2] (M) Initial Rate (M/s) Run 1 0.00130 0.00479 2.16 x 104 Run 2 0.00259 0.00479 4.30 x 10-4 Run 3 0.00612 0.00123 2.61 x 104 Run 4 0.00612 0.00246 5.22 x 104 (A) (B) (C) (D) (E) Rate = k [NO2] [F2] Rate = k [NO2]?[F2] Rate = k [NO2] Rate = k [NO2]?[F2]0.5 Rate = k [NO2] [F2]0.5
Using the data given for Question 19 (and the rate law that you derived), what is the value of the rate constant
(k) with the appropriate units?
(A)
(B)
(C)
(D)
(E)
34.7 s1
2.88 x 102 M1s-1
34.7 M's1
6.23 x 106 s1
2.88 x 102 s1
Transcribed Image Text:Using the data given for Question 19 (and the rate law that you derived), what is the value of the rate constant (k) with the appropriate units? (A) (B) (C) (D) (E) 34.7 s1 2.88 x 102 M1s-1 34.7 M's1 6.23 x 106 s1 2.88 x 102 s1
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