Direct oxidation TS zeolite catalyst H202 H20

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter29: Organic Polymer Chemistry
Section: Chapter Questions
Problem 29.9P
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The image shows the synthesis of epoxide using propylene catalyzed by molybdenum. While through direct oxidation, propylene reacts with hydrogen peroxide catalyzed by TS zeolite. What is the % atom economy for epoxide production concerning this
greener process? Do not include the % sign, only numerical value, and 2 significant figures for the final value.
yoou
you
O2
Mo catalyst
you
OOH
OH
Overall reaction
O2
+ C4H10
(CH3)3COH
42
32
58
58
74
58
58
Atom economy =
x 100% =
x 100% = 44%
58+42+32
58+74
Direct oxidation
TS zeolite catalyst
H2O2
Transcribed Image Text:The image shows the synthesis of epoxide using propylene catalyzed by molybdenum. While through direct oxidation, propylene reacts with hydrogen peroxide catalyzed by TS zeolite. What is the % atom economy for epoxide production concerning this greener process? Do not include the % sign, only numerical value, and 2 significant figures for the final value. yoou you O2 Mo catalyst you OOH OH Overall reaction O2 + C4H10 (CH3)3COH 42 32 58 58 74 58 58 Atom economy = x 100% = x 100% = 44% 58+42+32 58+74 Direct oxidation TS zeolite catalyst H2O2
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