Draw the complete, detailed mechanism for the reaction shown here, which produces an amidine-a nitrogen analog to an ester. H NH C=N 1. 2. CH,ОH Benzonitrile An amidine
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- The Gabriel synthesis of primary amines discussed in Chapter 20 involves hydrolysis under basic conditions to release the amine. As shown in the reactions below, the amine can also be released by (a) hydrolysis under acidic conditions and (b) treatment with hydrazine. Draw the complete, detailed mechanisms for these reactions.provide the major product(s) for each of the following reactions. also, provide the mechanism for the last two reactionsN,N-Diacylamides can be prepared by treating an acylchloride with lithium nitride in a 3-to-1 ratio. Draw a complete, detailed mechanism for this reaction.
- The Gabriel–malonic ester synthesis, shown here, is used to make α-amino acids. Draw complete, detailed mechanisms for this set of reactions and draw the structure of the intermediate A.Propose a mechanism for the reaction shown here, which takes place under conditions that favor anDraw a detailed mechanism of the following reactions and determine the major product:
- a) Draw the mechanism for the reaction of a secondary amine with an acid chloride to make an amide.b) Explain what conditions (acid/basic/neutral; excess of one reagent, etc) are required to carry out this reaction in high yield, and why.Predict the product of the reaction between acetic anhydride and each of the following compounds. If no reaction is expected to occur, write “no reaction.” Draw the complete, detailed mechanism for each reaction that does occur.(a) H2O; (b) CH3NH2, pyridine; (c) (S)-butan-2-ol; (d) diethyl etherDraw a complete, detailed mechanism for the reaction shown here.
- Draw a complete, detailed mechanism for the following reaction. A key intermediate is provided.Predict the major products of the following reactions. Draw the complete, detailed mechanism that leads to the formation of each of those products.Predict and identify the reactants of the following products. Draw the COMPLETE mechanism.