Table 3.2odi ensiminimiCVEWLE-FSubstituent, Xbx stl-H lliw sadi sah asupstotoutieng Isixs-0.2od 24swin modis -0.2-0.5-0.511-CN-CI-Br1015Energy differences (AG) for equilibration of monosubstituted clcyclohexanes, C6H₁Xzadobadiam mord inprobibaabruogmos.sondy the 101-gur sel-OCH3-OH-COOH-CH3 CH#-CH=CH₂-CH₂CH3-CH(CH3)2AG (equatorial-axial) moc(kcal mol-1)-C6H5-C(CH3)3-C=CHDimethylcycloban-0.5goils, bars in cafH H-0.6-1.0-1.4-1.7-1.7-1.8 T-2.1-2.9-5.4EnergyvodeJoy wibor bfolavalvulad(Less stable conformations:half-chair, boat, twist-boat)H+AGⓇ314H-Xat E sugia Draw the conformation for methoxycyclohexane with the methoxy group axial and theconformation with the methoxy group equatorial, include all hydrogen atoms on cyclohexaneand label each as axial or equatorial. Using the values from Table 3.2, which conformation ismore stable and by how much energy? Calculate the Keq for the equilibrium between axialand equatorial cyclohexane at 298 K. Calculate the percentage of each conformation presentat this temperature.

Answered: Image /qna-images/answer/fdc480bc-589b-4dfe-b2e1-760279f27a5b.jpg

Draw the conformation for methoxycyclohexane with the methoxy group axial and the conformation with the methoxy group equatorial, include all hydrogen atoms on cyclohexane and label each as axial or equatorial. Using the values from Table 3.2, which conformation is more stable and by how much energy? Calculate the Keq for the equilibrium between axial and equatorial cyclohexane at 298 K. Calculate the percentage of each conformation present at this temperature.

Draw the conformation for methoxycyclohexane with the methoxy group axial and the conformation with the methoxy group equatorial, include all hydrogen atoms on cyclohexane and label each as axial or equatorial. Using the values from Table 3.2, which conformation is more stable and by how much energy? Calculate the Keq for the equilibrium between axial and equatorial cyclohexane at 298 K. Calculate the percentage of each conformation present at this temperature.

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter2: Alkanes And Cycloalkanes

Section2.5: Conformations Of Alkanes And Cycloalkanes

Problem 2.9P: Following is a chair conformation of cyclohexane with the carbon atoms numbered 1 through 6. (a)...

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