Draw the Lewis structure of PF3 and PI3.  Determine which statement best describes the Lewis acid or base properties of the compounds.     a). PF3 and PI3 both have phosphorus sp2 hybridized with a lone pair in a p orbital.  Both can act as Lewis acids.  The p orbital with the lone pair on PI3 is smaller than on PF3.   b) PF3 and PI3 both have phosphorus sp2 hybridized with a lone pair in a p orbital.  Both can act as Lewis bases.  The p orbital with the lone pair on PI3 is smaller than on PF3.   c) PF3 and PI3 both have phosphorus sp3 hybridized with a lone pair in an sp3 orbital.  Both can act as Lewis acids.  The sp3 orbital with the lone pair on PI3 is smaller than on PF3.   d) PF3 and PI3 both have phosphorus sp3 hybridized with a lone pair in an sp3 orbital.  Both can act as Lewis bases.  The sp3 orbital with the lone pair on PI3 is larger than on PF3.   e) PF3 and PI3 both have phosphorus sp2 hybridized with a lone pair in a p orbital.  Both can act as Lewis bases.  The p orbital with the lone pair on PI3 is larger than on PF3.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter4: Acids And Bases
Section: Chapter Questions
Problem 4.35AP: The sec-butyl cation can react as both a Brnsted-Lowry acid (a proton donor) and a Lewis acid (an...
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Draw the Lewis structure of PF3 and PI3.  Determine which statement best describes the Lewis acid or base properties of the compounds.

 

 

a). PF3 and PI3 both have phosphorus sp2 hybridized with a lone pair in a p orbital.  Both can act as Lewis acids.  The p orbital with the lone pair on PI3 is smaller than on PF3.

 

b) PF3 and PI3 both have phosphorus sp2 hybridized with a lone pair in a p orbital.  Both can act as Lewis bases.  The p orbital with the lone pair on PI3 is smaller than on PF3.

 

c) PF3 and PI3 both have phosphorus sp3 hybridized with a lone pair in an sp3 orbital.  Both can act as Lewis acids.  The sp3 orbital with the lone pair on PI3 is smaller than on PF3.

 

d) PF3 and PI3 both have phosphorus sp3 hybridized with a lone pair in an sp3 orbital.  Both can act as Lewis bases.  The sp3 orbital with the lone pair on PI3 is larger than on PF3.

 

e) PF3 and PI3 both have phosphorus sp2 hybridized with a lone pair in a p orbital.  Both can act as Lewis bases.  The p orbital with the lone pair on PI3 is larger than on PF3.

 

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