Draw the major organic products obtained from the reactions below. Be mindful of stereochemistry and regioselectivity. If stereochemistry is included in the product, note that the diast/enant is also included, but not provided due to space. Assume one equivalent unless stated otherwise, or if the reagent is a solvent, oxidant or reductant. 1. 1. SOCI2, pyridine 2. NaOH, H20 Me 3. D2, Pd/C, EtOAc Me A Me Me Me Me .. 'D Me Me D Me Me

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter9: Addition Via Cyclic Intermediate
Section: Chapter Questions
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Draw the major organic products obtained from the reactions below. Be mindful of stereochemistry and
regioselectivity. If stereochemistry is included in the product, note that the diast/enant is also included, but
not provided due to space. Assume one equivalent unless stated otherwise, or if the reagent is a solvent,
oxidant or reductant.
1.
Me
1. SOCI2, pyridine
2. NaOH, H2O
OH
3. D2, Pd/C, EtOAC
Ме
A
В
Me
Me
Me
Me
'D
'D
Me
Me D
Me D
Ме
2.
Me
но.
1. Hо(ОАc)2, МеОН
„Me
2. NABH4, H2O, NaOH
Me
A
В
Me, Et
Ме, ОМе
Me
Ме, Н
Ме
Ме, ОМе
Ме
но.
но
но
-Me
OMe
Me
Me
Me
1
Transcribed Image Text:Draw the major organic products obtained from the reactions below. Be mindful of stereochemistry and regioselectivity. If stereochemistry is included in the product, note that the diast/enant is also included, but not provided due to space. Assume one equivalent unless stated otherwise, or if the reagent is a solvent, oxidant or reductant. 1. Me 1. SOCI2, pyridine 2. NaOH, H2O OH 3. D2, Pd/C, EtOAC Ме A В Me Me Me Me 'D 'D Me Me D Me D Ме 2. Me но. 1. Hо(ОАc)2, МеОН „Me 2. NABH4, H2O, NaOH Me A В Me, Et Ме, ОМе Me Ме, Н Ме Ме, ОМе Ме но. но но -Me OMe Me Me Me 1
6.
Me.
H2 (xs), Pd/C
„Me
(1 atm pressure)
MeOH
Ме
A
Me.
Me
Me.
Ме.
Me
„Me
Me
Me
Ph
Ph
Ph
Me
Me
Me
Me
7.
Me
HO
CF3
Me
A
B
D
ÇF3
Me
Ме
Me
Me
CF3
Me F3C
Me Me
O.
Me-
Me
Me
Me
Me
Me
Me
8.
Me
1. H2SO4, H20 A
2. ВНз, THF
3. Н,О2, NaOн
A
D
Me
Me
Me
Me
Он
Transcribed Image Text:6. Me. H2 (xs), Pd/C „Me (1 atm pressure) MeOH Ме A Me. Me Me. Ме. Me „Me Me Me Ph Ph Ph Me Me Me Me 7. Me HO CF3 Me A B D ÇF3 Me Ме Me Me CF3 Me F3C Me Me O. Me- Me Me Me Me Me Me 8. Me 1. H2SO4, H20 A 2. ВНз, THF 3. Н,О2, NaOн A D Me Me Me Me Он
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