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- draw an electron-pushing mechanism that shows the formation of the anti looking products using AE then SN2 mechanistic pathwayDraw the mechanism that shows how α-D-allopyranose converts to α-D-allofuranose under acidic conditions.Draw a mechanism for the conversion of glucose from its aldehyde form to its hemiacetal form and then to its methyl glycoside (acetal) form under acidic conditions. Show all bond breaking and bond forming steps; show all intermediates.
- Draw the product formed when attached compound is treated with two equivalents of CH3CH2CH2CH2MgBr followed by H2O.Draw the mechanism that shows how α-D-allopyranose converts to β-D-allopyranose under acidic conditions.What ring-closing metathesis product is formed when each substrate is treated with Grubbs catalyst under high-dilution conditions?
- Choose one answer from each parenthesis. The identity of Structure A is represented by the structure labelled (SAT / MAT / CAT / BAT / WAT / RAT / NAT) while that of Structure B is labelled (SAT / MAT / CAT / BAT / WAT / RAT / NAT). The missing reagent in the first reaction is (dilute H2SO4 / H2O / MCPBA / Br2 and water).identify the reagents that will accomplish the following eneatioselective transformationThe following isomerization reaction, drawn using D-glucose as starting material, occurs with all aldohexoses in the presence of base. Draw a stepwise mechanism that illustrates how each compound is formed.
- Draw a mechanism for the Fischer esterification to synthesize Wintergreen.Draw a detailed mechanism for the bromination of ethyl phenylacetate with NBS.Draw mechanism for fischer esterification using the reagents benzoic acid, methanol and sulfuric acid using the general mechanism attached as reference. HINT: You just need to replace the Rs in the general mechanism for the actual groups in your reagents.