Draw the mechanisms for each reaction Br2 (1.0 equiv.), HOAC NaOA H2O2 Br (aq., 30 wt-%, 5.5 equiv.) HO HO (1.5 equiv.), 20°C ÓMe NaOH (aq., 2 wt-%) ÓMe 22 23 HO. Br Br CH2l2 (1.5 equiv.), K2CO3 (1.5 equiv.), DMF, 100°C, 1 h HO OMe ÓMe ÓMe 24 (91% from 22) 25 (74%)

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter19: Eas: Electrophilic Aromatic Substitution
Section: Chapter Questions
Problem 45E
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Draw the mechanisms for each reaction
Br2 (1.0 equiv.),
HOẠC NaOA
H2O2
Br (aq., 30 wt-%,
5.5 equiv.)
HO
HO
NaOH
(1.5 equiv.), 20°C
ÓMe
ÓMe
(aq., 2 wt-%)
22
23
HO.
Br
Br
CH2l2 (1.5 equiv.), K2CO3
(1.5 equiv.), DMF, 100°C, 1 h
HO
ÓMe
ÓMe
e
24 (91% from 22)
25 (74%)
Transcribed Image Text:Draw the mechanisms for each reaction Br2 (1.0 equiv.), HOẠC NaOA H2O2 Br (aq., 30 wt-%, 5.5 equiv.) HO HO NaOH (1.5 equiv.), 20°C ÓMe ÓMe (aq., 2 wt-%) 22 23 HO. Br Br CH2l2 (1.5 equiv.), K2CO3 (1.5 equiv.), DMF, 100°C, 1 h HO ÓMe ÓMe e 24 (91% from 22) 25 (74%)
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