Answered: Draw the principal form of alanine at…

Draw the principal form of alanine at pH 2.00. At pH 10.00 where H2A+ -> H+ + HA has a pKa of 2.348 and HA -> H+ + A- has a pKa of 9.867

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter26: Biomolecules: Amino Acids, Peptides, And Proteins

Section26.1: Structures Of Amino Acids

Problem 1P: How many of the -amino acids shown in Table 26-1 contain aromatic rings? How many contain sulfur?...

See similar textbooks

Related questions

Q: Calculate the equilibrium constant for the following reaction at 25 \deg C. What species is dominant…

A: The equilibrium constant, Keq, for a reaction is defined as the ratio of the concentrations of the…

Q: At a particular temperature, the solubility of In2(SO4)3 in water is 0.0061 M. What is the value of…

Q: ionic bond hydrogen bond Answer Bank hydrophobic interaction disulfide bond Identify the major force…

A: The major force controlling the tertiary structure of proteins is the hydrophobic effect. This force…

Q: Give introduction step and give me the answer with proper explanation no need to upload any image…

A: Step 1: Step 2: Step 3: Step 4:

Q: None

A: According to the VSEPR theory, SeH2 has two bond pairs and two lone pairs. Hence, the electron pair…

Q: None

Q: In addition to desired product (Zingerone), It is normal in the second step of attached experiment…

A: GroupChemical shiftAtomsSplittingremarkOH9.961singletphenolOH4.81singletalcoholCH6.591doublet…

Q: Use cell potential to calculate an equilibrium constant. Calculate the cell potential and the…

A: For the first question, we need to determine the Eo cell of the reaction We need to identify what…

Q: please give Step by Step Solution Otherwise i give you DISLIKE !!

A: The objective of the question is to complete a synthesis reaction using the SN2 mechanism. The SN2…

Q: 1016 3. Using Hess' Law, Calculate the standard heat of formation of copper(I) oxide given the…

A: Step 1:Introduction to question :Given ,Reaction 1 : CuO(s) → Cu(s) + ½ O2(g) Δ.Η° = 157.3…

Q: You have two G’s and two temperatures. Use these to solve for H and S. TEMP1 - 296.57 K TEMP2 - 340…

Q: 2

A: a) Br elimination of 2-bromo-2-methyl butane with sodium ethoxide follows Zaitsev's rule giving…

Q: 8. Give the final product 1) [H+], E+ OH (2 eq) 2) Me Mg Br 3JH20 4)430+ OH a) رها он он Ј I

A: In case of any doubt feel free to ask.

Q: A chemist fills a reaction vessel with 0.618 g aluminum hydroxide (Al(OH),) solid, 0.222 M aluminum…

A: In this problem, the concentrations of solutions given are not 1M at 25oC and 1 atm. This makes the…

Q: 4. Draw possible structures for isomeric compounds with the molecular formula C6H10O that contain…

A: Here are the possible structures for isomeric compounds with the molecular formula C6H10O containing…

Q: Nitric oxide (NO) reacts with H2 to form N2O and H2O. It is known that there are two elementarysteps…

A: The rate law tells us which is the rate determining step.The slowest step is the rate determining…

Q: 24. Von Franz's work on alchemy focuses on: A) "The symbolic nature of alchemical texts and…

A: A) "The symbolic nature of alchemical texts and practices." is correct because:Marie-Louise von…

Q: None

A: The IUPAC nomenclature of organic compounds follows this naming format:Writing the name of organic…

Q: i dont want hand writting image

A: The objective of the question is to identify the alcohol starting material and the reagents required…

Q: involve titrating a 100.0 mL sample of 0.20 M HF is titrated with 0.10 M KOH. The Ka of HF is 3.5 ×…

A: Step 1: Calculate the initial moles of acid and base added in the mixture/solution. Moles of HF =…

Q: 8. Consider the reaction below for the conversion nitrogen dioxide to nitric oxide and O2 using bond…

A: The chemical equation we are considering is:2 NO2(g) -> 2 NO(g) + O2(g)First, let's identify the…

Q: None

Q: Provide the conplete mechanism. Need both formation of diazonium ion from the nitrosonium ion and…

A: Step 1:Sodium nitrite when protonated in presence of acid it gives nitrous acid. The nitrosonium ion…

Q: None

A: Step 1: Step 2: Step 3: Step 4:

Q: Predict the major products of the following reaction. Be sure to show the stereochemistry of the…

A: Step 1: Step 2:Mechanism Step 3: Step 4:

Q: Describe the energy in natural gas and the way in which it's converted to electrical energy?

A: Step 1: Natural gas is primarily composed of methane, with smaller amounts of other hydrocarbons…

Q: Drow mechanism and full details

A: Step 1: Cl2 + heat does chlorination. Step 2: H2O acts as a nucleophile and substitutes chlorine.…

Q: None

A: Step 1: Step 2: Step 3: Step 4:

Q: 5.30 The average enthalpy change of vaporization of benzene between room temperature and the normal…

A: Approach to solving the question: Detailed explanation: Examples: Key references:

Q: 68) A 25.0-mL sample of 0.150 M HN3 is titrated with a 0.150 M NaOH solution. What is the pH after…

A: Given: VHN3=25.0mL;[HN3]=0.150M;VNaOH=13.3mL;[OH−]=0.150MKa=1.9x10−5;pH=???Step 1: Write the…

Q: One of the triggering condition for a fusion of Coronovirus (COVID-19) with a human cell is an…

A: The inability to effectively dispose of CO2 from the bloodstream, referred to as respiration…

Q: What role does silica gel play in the Fisher esterification reaction?

A: By removing the water from the reaction mixture, silica gel helps to drive the reaction forward…

Q: Identify the major and minor product(s) that are expected for the following reaction. Select all…

Q: 1) Show the products for the following aldol condensation. Products only, no mechanism. OH aq

A: Step 1: alpha hydrogen having carbonyl compounds in presence of dilute base produces α, β…

Q: Draw one of the possible diastereomers of the molecule shown below. Use a dash or wedge bond to…

A: A diasteromer of a compound is the isomer that unlike enentiomer is not a mirror image reflection of…

Q: Calculate the standard all potentials given the following data: + 2+ Cu (aq) + 2e¯ → Cu(s), E° › ·…

A: The objective of the question is to calculate the standard cell potential for the given reactions.…

Q: Identify the correct dipole for the C-O bond in the Lewis structure of acetone shown using the…

A: The objective of the question is to identify the correct dipole for the C-O bond in the Lewis…

Q: the ph of a 0.010M solution of just HOCL in water is 4.8 . What is H+ in that solution? b) what is…

Q: please answer in text form and in proper format answer with must explanation , calculation for each…

A: In case of any doubt please feel free to ask.

Q: Please solve and show all work.

A: Step 1: When alkene treated with Br2 it gives trans vicinal dihalide as a product. This vicinal…

Q: What is the major product of the following reaction? CH3 Br₂ ? + H₂O L CH3 IV. CH3 OH Br OH V. CH3…

A: Step 1:

Q: please give Step by Step Solution otherwise i give you DISLIKE !

A: Step 1:Nucleophilic attack by phenyl magnesium bromide (grignard reagent) to the carbonyl carbon of…

Q: a solution of cupric sulphate is used at a blood donor clinic to test donor blood for low iron.…

Q: Please provide an explanation with the answer

A: Step 1:According to CIP rule : Higher atomic number gets higher priority. For stereocenter 2,…

Q: Provide the IUPAC name for the following thiol: SH

A: For IUPAC naming •Determine the longest continuous chain of carbon atoms that forms the ring. This…

Q: www-awu.aleks.com/alekscgi/x/Isl.exe/10_u-IgNslkr7j8P3JH-IQUHIQg6bJxmeSyVPHOEB1plef9xyC5Ca9Qllg7siQ-…

A: Step 1:naming process for each molecule:1. 2-Hydroxybutanal a. Identify the Longest Carbon Chain…

Q: Answer all three please ✓ 2 TABLE 13.2 Inorganic Compounds - Be sure to show the proper geometries!…

Q: Correct the following, there are 2 mistakes Naz Cr₂Oz H₂504 H₂O HO TSOH NH3 NH

A: The objective of the question is to identify and correct the two mistakes in the given list of…

Q: Determine whether the following will proceed via SN1, SN2, E1 or E2 reaction. Draw the major…

Q: Retro aldol: H. NaOH H₂O H. HTH "j"82f NaOH

Question

Draw the principal form of alanine at pH 2.00. At pH 10.00 where H2A+ -> H+ + HA has a pKa of 2.348 and HA -> H+ + A- has a pKa of 9.867

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step by step

Solved in 2 steps

SEE SOLUTION Check out a sample Q&A here

Similar questions

At very low pH, alanine is a diprotic acid that can be represented as H3N1-CH(CH3)-COOH. The pKa of the carboxyl group is 2.3, and the pKa of the UNH1 3 group is 9.7.(a) At pH 7, what fraction of the amino acid molecules dissolved in an aqueous solution will have the form H3N1-CH(CH3)-COO2?(b) What fraction of the molecules at this pH will havethe form H2N-CH(CH3)-COOH?
(a) The isoelectric point (pI) of phenylalanine is pH 5.5. Draw the structure of the major form of phenylalanine at pHvalues of 1, 5.5, and 11.(b) The isoelectric point of histidine is pH 7.6. Draw the structures of the major forms of histidine at pH values of 1, 4,7.6, and 11. Explain why the nitrogen in the histidine ring is a weaker base than the a-amino group.(c) The isoelectric point of glutamic acid is pH 3.2. Draw the structures of the major forms of glutamic acid at pH valuesof 1, 3.2, 7, and 11. Explain why the side-chain carboxylic acid is a weaker acid than the acid group next to thea-carbon atom
What is the correct structure for the peptide SGHKRY at pH 5.0?
Taking the structure of the amino acids into account, give a comparative discussion of these pK values : Alanine : 2.34 : 6.1 : 9.70 Histidine: 1.82 : 9.17
Single hydrolysis on the following polypeptide 2. Draw the fisher projection of phenylalanine at pH 1, 7 and 12
Draw the form of aspartate that predominates at the following pH values: pH = 11.0
22-35 Why is histidine considered a basic amino acid when the pKa of its side chain is 6.0?
22-71 Which amino acid side chain is most frequently involved in denaturation by reduction?
What is the net charge on valine at pH 1?b. at pH 7? c. at pH 14? What is the net charge on Phe-Asp at each pH?a. pH 1? b. at pH 7? c. at pH 14?
Please draw the asparagine and aspartic acid. Make sure to draw them at pH 7! On each amino acid, record the protons that can dissociate, their respective pKa's, and the overall net charge at pH 7.
In the case of serine, threonine and tyrosine they have the -OH group in their residue. I'm wondering even though all of them has the -OH groups in their residue. but only the tyrosine has the pKa value with the -OH grouup.
Draw the structure of alanine in a solution at pH = 0