Draw the structure(s) of the major organic product(s) of the following reaction. 1. Dioxane / reflux Br 2 aqueous HCI [Review Topics] [References] . You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • 9 • Do not include lone pairs in your answer. They will not be considered in the grading. Do not include the amine from which the enamine was derived. If no reaction occurs, draw the organic starting material. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu.
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- 1) Based on the Material Safety Data Sheets (MSDS) for the compounds, which of the compounds in this experiment is the most hazardous, and why (you have been given a representative aryl halide rather than all of the alkenes – as the products are all new, there’s not a simple answer to gauge their potential hazard)? 2,3-dihydrofuran,2-Mercaptobenzimidazole,Selectfluor, Dimethylformamide,dichloromethane-methylene chloride.Assume that 2-chloropropane reacts with CN− in an SN2 reaction. Use the JSME editor () to draw the structure of the substitution product of the reaction. The guide on how to draw your structure can be found here Important Note: When drawing the structures in the JME editor please adhere to the following formats: 1. If the nucleophile is OH−, DO NOT manually add the "H" to the final product 2. If the nucleophile is CN−, be sure to include the appropriate bonding between the C and N in the final productDraw structural formulas for the α,β-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could be used in a synthesis of the compound shown below.You do not have to consider stereochemistry.In cases where there is more than one answer, just give one.If a structure has a copper-lithium bond, draw the lithium ion in a separate sketcher.Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.Separate multiple reactants using the + sign from the drop-down menu.
- Write structures for the carbonyl electrophile and enolate nucleophile that react to give the aldol below. You do not have to consider stereochemistry. Draw the enolate nucleophile in its carbanion form. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple reactants using the + sign from the drop-down menu.1. A student chemist in an attempt to synthesise compound B from the aromatic aldehyde. Use the flow equation to answer I and II .Image attached below I)Predict the chemical name of compound B II)What is the reaction name for the chemical transformation of A to BDraw the structure(s) of the major organic product(s) obtained after workup of the following reaction. Use the wedge/hash bond tools to indicate stereochemistry where it exists. If no reaction occurs, draw the organic starting material. Draw structure(s) of product(s) after aqueous workup. Include counter-ions, e.g., Na+, I-, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
- Fill in the fields (reagent or products) left blank in the reaction below.Friedel-Crafts Alkylation, based on substituted benzene reaction, including reactivity based on electron donating and withdrawing group and also discuss the possible positions (Ortho, Meta and Para) for the new group. Explain if there is polysubstitution occurs. Keeping the reaction mixture in the ice bath and adding the reagent slowly by continuously stirring is the key point of success.Enolates are formed by deprotonation of an α-carbon hydrogen. Answer the following questions about enolate formation. In the molecule shown, select the α-carbon hydrogen that would be removed to form an enolate when sodium hydroxide is used as a base. (use photo to answer this question). Then, Draw the thermodynamic enolate that results for the molecule in Part 1. Draw only the enolate resonance form that includes a formal charge on the α carbon. Be sure to indicate that formal charge as well as any lone pair of electrons in your answer.
- Draw a flowchart showcasing the purification step done for the reaction under basic conditions (the basic reaction of 4-methoxyacetophenone with bleach, sodium hydroxide, and acetone), starting from the crude reaction mixture all the way to the isolated solid product. Assume for this drawing that the reaction was complete, and that none of the intermediates are found in the crude mixture. There may still be however traces of your starting material in the crude mixture, along with any excess reagentsReaction with Alcohols (esterification)a. Mix 1 mL of glacial acetic acid, 1 mL of ethyl alcohol and 3 drops ofconcentrated sulfuric acid (CAUTION!). Cautiously note the odor.Result: ___________________________________________________________________To what compound is the odor due? ________________________________________Equation: _________________________________________________________________b. To about 0.1 gm of salicylic acid in a test tube, add 1 mL of methyl alcoholand 3 drops of concentrated sulfuric acid (CAUTION!). Heat the mixture gentlyfor 1 – 2 minutes, then pour the mixture into about 20 mL of cold watercontained in a beaker. Observe the odor of the product formed. _____________What compound produces this odor? ______________________________________Equation: ______________________________________________________________The addition of an alcohol to an acid chloride is an example of alcoholysis (alcohol addition with bond breakage). Consider the alcoholysis reaction below and answer the questions that follow. 1. Show the tetrahedral intermediate that is formed after the nucleophilic addition of the alcohol to the acid chloride. Be sure to include all lone pair electrons and formal charges on your intermediate structure. 2. Show the final product of this alcoholysis reaction that forms after the intermediate you made in Part 1. Do not include inorganic or charged products in your answer. Be sure to include all lone pair electrons and formal charges.