drow the electronic configuration of iron in heme part of hemoglobine knowing that it is a complex compound and expect: a. types and number of chelating agents b. the coordination covalent bond orbitals involved in oxygen /CO2 transportation.

Q: Identify the most likely second-row transition metal for each of the following: a. [M(CO);(NO)I b.…

A:

Q: What are the three basic methods for the resolution of optically active complexes.

A: Basic methods for the resolution of optically active complexes:

Q: Which species are more likely to act as ligands? (a) Positivelycharged ions or negatively charged…

A: (a) Determine the species that act like as ligands among positively charged ions or negatively…

Q: (b) What are the effects of r-donor and t-acceptor ligands on the splitting of metal d orbitals in…

A: Answer- When the ligands approach the central metal ion, d- or f-subshell degeneracy is broken due…

Q: drow the electronic configuration of iron in heme part of hemoglobine knowing that it is a complex…

A:

Q: draw the electronic configuration of platinium II in carboplatine (complex and expect the…

A: Since we only answer up to three sub parts, we'll answer the first three.  Please resubmit the…

Q: A transition metal, M, is coordinated in an octahedral fashion to the following ligands Two chloro…

A: We get a total of 6 Isomers.2 isomers where Cl atoms are trans.Since a sigma plane passes through…

Q: What is the coordination humber and geometry of the following structures: a.…

A: Coordination number is also called ligancy and the number of atoms, ions, or molecules holds its…

Q: ) Figure 5 shows four energy diagrams, labelled A to D. The diagrams depict possible configurations…

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Q: d-penicillamine is a well known copper chelating agent use for cases associated with copper…

A:

Q: What is the main purpose of using cold ethanol to wash the synthesized crystalline nickel(II)…

A: Ethyl alcohol is an excellent solvent.  It is also used for recrystallization. After production of…

Q: Which of the following statements about 10Dq is false? A. [VCl6]2- has a greater 10Dq than [VCl4]…

A: 10Dq is the splitting energy .  As there is strong field ligans sorroundinh the central atom , then…

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1. Linkage…

A: Linkage isomer :-       It is a isomer of coordination compound,  in which ambidentate ligands have…

Q: draw the electronic configuration of platinium II in cisplatine (complex and expect the followings:…

A: The charge of Pt in cis-platin is +2. It is a square planar complex. Its hybridisation is dsp2.

Q: (a) Give systematic names for the following formulas: - [Co(N3)(NH3)s]SO4 - KĄ[Fe(CN);ONO] -…

A: The nomenclature of the coordination complexes are  given below

Q: "Are all the organometallic complexes stable to moisture and temperature?" Explain.

A: the thermal stability organometallic compound generally decreases from the lightest to the heaviest…

Q: d. An analogous compound, [Cu(H₂O)6]2+ has a different arrangement of the eg and t2g orbitals. Draw…

A: Let us study the effect.

Q: Fe3+ (a hard metal) forms the n stable complex with which of tl Following bases: 1.

A: Hard metal forms stable complex with hard base.

Q: Write the formula for a complex formed between Fe³+ and ethylenediamine (NH, CH,CH,NH, ), with a…

A: Interpretation -  To write the formula formed for a complex  between Fe3+ and ethylenediamine with…

Q: Suppose that rather than reacting copper(II) with ammonia, you had reacted it with an ammonium salt,…

A: • It is given that rather than reacting copper(ll) with ammonia, one had reacted copper(Il) with an…

Q: Explain why there is no distinction between low and high-spin arrangements for an octahedral d8…

A:

Q: What do you understand by ‘denticity of a ligand’?

A: Introduction: In a coordination compounds, ligand donate electrons to the central metal atom to form…

Q: a) Trialkylphosphine and ammonia are both strong-field ligands. However, experimental data show that…

A: Solution for a, PR3 ligands cause higher Δo than the NH3 because PR3 is σ-donor as well as…

Q: Werner first published his thoughts concerning the possibiolity of chiral coordination compounds in…

A: Geometrical isomer Geometrical isomer having the same molecular formula and same structure but it…

Q: The stepwise stability constant in aqueous solution for the formation of copper complexes with NH3…

A:

Q: drow the electronic configuration of iron in heme part of hemoglobine knowing that it is a complex…

A: Hemoglobin exist in two forms oxy hemoglobin and deoxyhemoglobin. In deoxy form oxygen will not bind…

Q: Is it more thermodynamically favorable for ubiquinol to transfer electrons to cytochrome c or…

A:

Q: 1) Why are lanthanide  complexes always weak field in nature , second and third d-transition metal…

A: Hey, since there are multiple questions posted, we will answer first question. If you want any…

Q: The IR used to investigate the CO coordination to transition metal, why?

A: Carbon monoxide bonds to transition metals using "synergistic π* back-bonding

Q: In each the following generalized coordination complexes, M represents the central metal ion and L1,…

A: From given  Enantiomers are optical isomers which are mirror images to each other so we are finding…

Q: The stability of metal complexes with EDTA is due to the formation of? A) Zwitterion B) Chelate…

A: Correct Option :  B) Chelate complex

Q: The mass speetra g rhodrium carbonyl complex indicate & duriacing every peak at 748 amu, F20 amu 28…

A:

Q: b) Metal carbonyls are transition metal complexes of carbon monoxide (CO). Both carbon and oxygen…

A: The donor ability depends on the highest occupied molecular orbital (HOMO). Higher the energy a HOMO…

Q: catahedral” Cu (II) complexes are often described as having a (4+2)- coordination pattern. Suggest…

A:

Q: Will methylamine (CH3NH2) be a monodentate or abidentate ligand? With which of its atoms will it…

A: Will methylamine (CH3NH2) be a monodentate or a bidentate ligand? With which of its atoms will it…

Q: Write the formula for a complex formed between Ni? + and NH, with a coordination number of 5.…

A: Coordination complex is compound which contain central metal atom surrounded by non metal atoms or…

Q: Amino acids are important chelating ligands that bind to the metal through N and O atoms. Suppose…

A: The square planar complex is the complex having square planar geometry a central atom is surrounded…

Q: Determine the symmetry of the orbital groups for the donor sigma bonds (σ) of the ligand in an…

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Q: 1. The UV-visible spectrum of an aqueous solution of CuSO, (which contains a Cu2+ metal center)…

A: ∆Oct is an energy term, representing the energy gap between the splitted orbitals and have an…

Q: Considering a dissociative mechanism for octahedral complexes, explain why metallic centers with…

A: Second and third grade metals are larger compare to first grade metals.  Hence, there is less steric…

Q: Which of the following statements about 10Dq is false? A. In the [CoX(NH3)5]n+ complex, the color…

A: The energy difference in the coordination compound related to colour.In  Strong field ligand,higher…

Q: a. Briefly describe the chelate effect b. Give the structure of a ligand that will exhibit the…

A: The metal complex carrying the ligand that is chelating (two or more donating sites) is named as…

Q: draw the electronic configuration of platinium II in oxaplatine (complex and expect the followings:…

A: There are noval anticancer drugs based on transition metal complexes. Pt based anticancer drugs are…

Q: This is inorganic chemistry d-metal complexes. the book answer says that it is a d4 but i do not see…

A: here given complex CoNH33+ , related with d4 spectrum diagram, and both are inversely relation ,…

Q: (a) How would you account for the following: (i) Actinoid contraction is greater than lanthanoid…

A: i) The actinides have 5f orbitals whereas lanthanides have 4f orbitals filled. The 5f orbitals have…

Q: The (2-aminoethyl)phosphine ligand, acts as a bidentate ligand with metals of Transition. i) How…

A: The structure of (2-aminoethyl)phosphine ligand is

Q: What is the difference between a monodentate and a multidentate ligand? Is a chelating ligand…

A: A ligand contains 1 or more donor atoms which are coordinated to the central metal atom to form a…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.