d-penicillamine is a well known copper chelating agent use for cases associated with copper toxicities and metabolic copper excess related diseases like willson's disease. 1. write the copper electronic configuration in its second oxidation state through noble gas representation and show the location of valence electrons

d-penicillamine is a well known copper chelating agent use for cases associated with copper toxicities and metabolic copper excess related diseases like willson's disease. 1. write the copper electronic configuration in its second oxidation state through noble gas representation and show the location of valence electrons

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter14: Applications Of Ultraviolet-visible Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 14.7QAP: A 3.03-g petroleum specimen was decomposed by wet ashing and subsequently diluted to 500 mL in a...

See similar textbooks

Similar questions

You have been sent to India to investigate the occurence of goiter disease attributed to iodine deficency. As part of of your investigation, you must make field measurements of traces of Iodide(I-) in groundwater. The procedure is to oxidize I- to I2 and convert the I2 into an intensely colored complex with the dye brilliant green in the organic solvent toluene. a) A 3.15x10^-6 M solution of the colored complex exhibited an absorbance of 0.267 at 635nm in a 1.00cm cuvet. A blank solution made from distilled water in place of groundwater had an absorbance of 0.019. Find the molar absroptivity of the colored complex. b)The absorbance of an unknown solution prepared from ground water was 0.175. Find the concentration of the unknown.
Discuss the binding mode and geometry of the imido and cyclopentadienyl ligands in the tungsten complex below.
draw the electronic configuration of platinium II in carboplatine (complex and expect the followings: a. the charge of this drug b. the shape of its complex. c. the expected type of hybridization d. the number of coordination covalent bonds in this drug e. what is the pharmacological use of it
List the cobalt complexes in order of increasing Kstab values. Using one of the cobalt(II) complexes as an example, identify what the Kstab value represents and hence justify your order of stability above.
copper complex crystallises straightaway when synthesising but the cobalt complex required the solution to be concentrated and cooled before it is filtered to obtain product. what does this tell you about the realtive solubilities of the copper and cobalt complexes.
Regarding the formation of the tetracyanetoniquelate (II) complex answer:a.Demonstrates hybridization according to the valence bond theory and indicate itsgeometry.b. Demonstrate and explain the unfolding of the crystalline field in the formation of this ioncomplex.c. Demonstrate through a diagram of molecular orbitals and explain the formation of that ioncomplex according to the ligand field theory
(a) How would you account for the following: (i) Actinoid contraction is greater than lanthanoid contraction. (ii) Transition metals form coloured compounds.
Show the calculation of electrons for the complexes below using 18-electron count principle.
Report on the preparation of this complex
A 3.03-g petroleum specimen was decomposed by wet ashing and subsequently diluted to 500 mL in a volumetric flask. Cobalt was determined by treating 25.00-mL aliquots of this diluted solution as follows: Assume that the Co(II)-ligand chelate obeys Beer’s law, and calculate the percentage of cobalt in the original sample.
draw the electronic configuration of platinium II in oxaplatine (complex and expect the followings: a. the charge of this drug b. the shape of its complex. c. the expected type of hybridization d. the number of coordination covalent bonds in this drug e. what is the pharmacological use of it
1,Count up the 18-electron rule of the organometallic complex (Ferrocene) using covalent counting method.2. Draw the molecular orbital diagram for B2 and find the bond order?