Ethyl acetate is synthesized in a nonreacting solvent (not water) according to the following reaction: CH; CO,H+ C,HOH CH CO2C2H; + H20 K = 2.2 Acetic acid Ethanol Ethyl acetate For the following mixtures (a-d), wvill the concentration of H2O increase, decrease, or remain the same as equilibrium is established? a. [CH;CO,C, Hs] = 0.22 M, [H2O]= 0.10 M, [CH; CO,H] = 0.010 M, [C, H; OH] = 0.010 M %3D O increase O decrease O remain the same b. [CH,CO2C,Hs] = 0.22 M, [H20] = 0.0020 M. [CH,CO,H] = 0.0020 M, [C,H;OH] = 0.10 M O increase O decrease Oremain the same c. [CH;CO2C, Hs] = 0.88 M. [H20] = 0.12 M. [CH,CO,H] = 0.044 M, [C,H; OH] = 6.0 M increase O decrease O remain the same d. [CH3CO,C,H;] = 4.4 M, [H20] = 4.4 M. [CH; CO,H = 0.88 M. [C,H;OH] = 10.0 M O increase O decrease Oremain the same e. What must the concentration of water be for a mixture with [CH3 CO,C,Hs] =1.0 M, [CH3CO,H] = 0.10 M, and [C2Hs OH] = 7.0 M to be at equilibrium? Concentration
Ethyl acetate is synthesized in a nonreacting solvent (not water) according to the following reaction: CH; CO,H+ C,HOH CH CO2C2H; + H20 K = 2.2 Acetic acid Ethanol Ethyl acetate For the following mixtures (a-d), wvill the concentration of H2O increase, decrease, or remain the same as equilibrium is established? a. [CH;CO,C, Hs] = 0.22 M, [H2O]= 0.10 M, [CH; CO,H] = 0.010 M, [C, H; OH] = 0.010 M %3D O increase O decrease O remain the same b. [CH,CO2C,Hs] = 0.22 M, [H20] = 0.0020 M. [CH,CO,H] = 0.0020 M, [C,H;OH] = 0.10 M O increase O decrease Oremain the same c. [CH;CO2C, Hs] = 0.88 M. [H20] = 0.12 M. [CH,CO,H] = 0.044 M, [C,H; OH] = 6.0 M increase O decrease O remain the same d. [CH3CO,C,H;] = 4.4 M, [H20] = 4.4 M. [CH; CO,H = 0.88 M. [C,H;OH] = 10.0 M O increase O decrease Oremain the same e. What must the concentration of water be for a mixture with [CH3 CO,C,Hs] =1.0 M, [CH3CO,H] = 0.10 M, and [C2Hs OH] = 7.0 M to be at equilibrium? Concentration
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.9P
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