Exercise 6. The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kinetics of the aqueous reaction was observed several times at the same temperature: Mn²+ 2 Ce (aq) + TI+(aq) - 2 Ce³+ (aq) + T1³+ (aq) Initial rate of formation Experiment [Ce4+] initial [TI*]initial [Mn²+] of T1³+ (M s-¹) 1 0.0050 0.0025 0.0010 2.0 × 10-4 2 0.0050 0.0050 0.0010 2.0 × 10-4 3 0.0100 0.0025 0.0010 4.0 × 10-4 4 0.0050 0.0050 0.0030 6.0 × 10-4 a. Determine the rate orders with respect to Ce4+, to TI+, and to Mn2+ and explain or show how you arrived at your answers. Work/Explanation: i. The order with respect to Ce¹¹ is Work/Explanation: ii. The order with respect to Tl is, Page 4 of 9
Exercise 6. The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kinetics of the aqueous reaction was observed several times at the same temperature: Mn²+ 2 Ce (aq) + TI+(aq) - 2 Ce³+ (aq) + T1³+ (aq) Initial rate of formation Experiment [Ce4+] initial [TI*]initial [Mn²+] of T1³+ (M s-¹) 1 0.0050 0.0025 0.0010 2.0 × 10-4 2 0.0050 0.0050 0.0010 2.0 × 10-4 3 0.0100 0.0025 0.0010 4.0 × 10-4 4 0.0050 0.0050 0.0030 6.0 × 10-4 a. Determine the rate orders with respect to Ce4+, to TI+, and to Mn2+ and explain or show how you arrived at your answers. Work/Explanation: i. The order with respect to Ce¹¹ is Work/Explanation: ii. The order with respect to Tl is, Page 4 of 9
General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Chapter13: Rates Of Reaction
Section13.3: Dependence Of Rate On Concentration
Problem 13.4E
Related questions
Question
![Exercise
6.
The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kinetics
of the aqueous reaction was observed several times at the same temperature:
Mn²+
2 Ceª (aq) + TI+(aq) -- 2 Ce³+ (aq) + T1³+ (aq)
Initial rate of formation
[TI] initial
Experiment
[Ce4+] initial
[Mn²+]
of T1³+ (M s-¹)
0.0050
0.0025
0.0010
2.0 × 10-4
0.0050
0.0050
0.0010
2.0 × 10-4
0.0100
0.0025
0.0010
4.0 × 10-4
0.0050
0.0050-
0.0030
6.0 × 10-4
a. Determine the rate orders with respect to Ce4+, to TI*, and to Mn²+ and explain or show how you
arrived at your answers.
Work/Explanation:
1. The order with respect to Cet is
Work/Explanation:
ii. The order with respect to This
Page 4 of
AWNE
1
2
3
4](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbb8a976c-eb7b-4ed9-b029-cfa72f795dab%2F5114303b-0c0a-41f0-8117-262602145ca5%2Fjt0muk_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Exercise
6.
The oxidation of thallium(1) to thallium(III) by cerium(IV) is catalyzed by manganese(II). The kinetics
of the aqueous reaction was observed several times at the same temperature:
Mn²+
2 Ceª (aq) + TI+(aq) -- 2 Ce³+ (aq) + T1³+ (aq)
Initial rate of formation
[TI] initial
Experiment
[Ce4+] initial
[Mn²+]
of T1³+ (M s-¹)
0.0050
0.0025
0.0010
2.0 × 10-4
0.0050
0.0050
0.0010
2.0 × 10-4
0.0100
0.0025
0.0010
4.0 × 10-4
0.0050
0.0050-
0.0030
6.0 × 10-4
a. Determine the rate orders with respect to Ce4+, to TI*, and to Mn²+ and explain or show how you
arrived at your answers.
Work/Explanation:
1. The order with respect to Cet is
Work/Explanation:
ii. The order with respect to This
Page 4 of
AWNE
1
2
3
4
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 3 steps with 3 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
General, Organic, and Biological Chemistry
Chemistry
ISBN:
9781285853918
Author:
H. Stephen Stoker
Publisher:
Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:
9781337399425
Author:
Steven S. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
General, Organic, and Biological Chemistry
Chemistry
ISBN:
9781285853918
Author:
H. Stephen Stoker
Publisher:
Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:
9781337399425
Author:
Steven S. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning