1 Basic Concepts About Matter 2 Measurements In Chemistry 3 Atomic Structures And The Periodic Table 4 Chemical Bonding: The Ionic Bond Model 5 Chemical Bonding: The Covalent Bond Model 6 Chemical Calculations: Formula Masses, Moles, And Chemical Equations 7 Gases, Liquids, And Solids 8 Solutions 9 Chemical Reactions 10 Acids, Bases, And Salts 11 Nuclear Chemistry 12 Saturated Hydrocarbons 13 Unsaturated Hydrocarbons 14 Alcohols, Phenols And Ethers 15 Aldehydes And Ketones 16 Carboxylic Acids, Esters, And Other Acid Derivatives 17 Amines And Amides 18 Carbohydrates 19 Lipids 20 Proteins 21 Enzymes And Vitamins 22 Nucleic Acids 23 Biochemical Energy Production 24 Carbohydrate Metabolism 25 Lipid Metabolism 26 Protein Metabolism Chapter14: Alcohols, Phenols And Ethers
14.1 Bonding Characteristics Of Oxygen Atoms In Organic Compounds 14.2 Structural Characteristics Of Alcohols 14.3 Nomenclature Of Alcohols 14.4 Isomerism For Alcohols 14.5 Important Commonly Encountered Alcohols 14.6 Physical Properties Of Alcohols 14.7 Preparation Of Alcohols 14.8 Classification Of Alcohols 14.9 Chemical Reactions Of Alcohols 14.10 Structural Characteristics Of Phenols 14.11 Nomenclature For Phenols 14.12 Physical And Chemical Properties Of Phenols 14.13 Occurrence Of And Use For Phenols 14.14 Structural Characteristics Of Ethers 14.15 Nomenclature For Ethers 14.16 Occurrence Of And Use For Ethers 14.17 Isomerism For Ethers 14.18 Physical And Chemical Properties Of Ethers 14.19 Cyclic Ethers 14.20 Thiols: Sulfur Analogs Of Alcohols 14.21 Thioethers: Sulfur Analogs Of Ethers Chapter Questions Section: Chapter Questions
Problem 14.1EP Problem 14.2EP Problem 14.3EP Problem 14.4EP Problem 14.5EP Problem 14.6EP Problem 14.7EP Problem 14.8EP Problem 14.9EP Problem 14.10EP Problem 14.11EP: Write a condensed structural formula for each of the following alcohols. a. 2-Methyl-1-propanol b.... Problem 14.12EP: Write a condensed structural formula for each of the following alcohols. a. 2-Methyl-2-heptanol b.... Problem 14.13EP Problem 14.14EP Problem 14.15EP Problem 14.16EP Problem 14.17EP Problem 14.18EP Problem 14.19EP: Each of the following alcohols is named incorrectly. However, the names give correct structural... Problem 14.20EP Problem 14.21EP Problem 14.22EP Problem 14.23EP Problem 14.24EP Problem 14.25EP Problem 14.26EP Problem 14.27EP Problem 14.28EP Problem 14.29EP Problem 14.30EP Problem 14.31EP Problem 14.32EP Problem 14.33EP Problem 14.34EP Problem 14.35EP: Explain why the boiling points of alcohols are much higher than those of alkanes with similar... Problem 14.36EP: Explain why the water solubilities of alcohols are much higher than those of alkanes with similar... Problem 14.37EP Problem 14.38EP Problem 14.39EP Problem 14.40EP: Which member of each of the following pairs of compounds would you expect to be more soluble in... Problem 14.41EP: Determine the maximum number of hydrogen bonds that can form between an ethanol molecule and a.... Problem 14.42EP: Determine the maximum number of hydrogen bonds that can form between a methanol molecule and a.... Problem 14.43EP Problem 14.44EP Problem 14.45EP Problem 14.46EP Problem 14.47EP: Classify each of the following alcohols as a primary, secondary, or tertiary alcohol. Problem 14.48EP: Classify each of the following alcohols as a primary, secondary, or tertiary alcohol. Problem 14.49EP: Classify each of the following alcohols as a primary, secondary, or tertiary alcohol. a. 1-pentanol... Problem 14.50EP: Classify each of the following alcohols as a primary, secondary, or tertiary alcohol. a. 1-butanol... Problem 14.51EP Problem 14.52EP Problem 14.53EP Problem 14.54EP Problem 14.55EP Problem 14.56EP Problem 14.57EP Problem 14.58EP Problem 14.59EP Problem 14.60EP Problem 14.61EP: The alcohol 2,2-dimethyl-1-butanol cannot be dehydrated. Explain why. Problem 14.62EP Problem 14.63EP Problem 14.64EP Problem 14.65EP: Draw the structure of the aldehyde or ketone produced when each of the alcohols in Problem 14-63 is... Problem 14.66EP: Draw the structure of the aldehyde or ketone produced when each of the alcohols in Problem 14-64 is... Problem 14.67EP Problem 14.68EP Problem 14.69EP Problem 14.70EP Problem 14.71EP: Three isomeric pentanols with unbranched carbon chains exist. Which of these isomers, upon... Problem 14.72EP Problem 14.73EP Problem 14.74EP Problem 14.75EP Problem 14.76EP Problem 14.77EP Problem 14.78EP Problem 14.79EP Problem 14.80EP Problem 14.81EP Problem 14.82EP Problem 14.83EP Problem 14.84EP Problem 14.85EP Problem 14.86EP Problem 14.87EP Problem 14.88EP Problem 14.89EP Problem 14.90EP Problem 14.91EP Problem 14.92EP: Classify each of the following compounds as an ether, an alcohol, or as neither an ether or alcohol. Problem 14.93EP: Draw or write the following for the simplest ether (fewest carbon atoms) in which both R groups... Problem 14.94EP: Draw or write the following for the simplest ether (fewest carbon atoms) in which the R groups... Problem 14.95EP Problem 14.96EP Problem 14.97EP Problem 14.98EP Problem 14.99EP Problem 14.100EP Problem 14.101EP Problem 14.102EP Problem 14.103EP Problem 14.104EP Problem 14.105EP Problem 14.106EP Problem 14.107EP Problem 14.108EP Problem 14.109EP Problem 14.110EP Problem 14.111EP Problem 14.112EP Problem 14.113EP Problem 14.114EP: Give common names for all ethers that are constitutional isomers of butyl methyl ether. Problem 14.115EP: How many isomeric ethers exist when the R groups present in the ether are a. C1 and C3 alkyl groups... Problem 14.116EP Problem 14.117EP Problem 14.118EP: Draw condensed structural formulas for the following. a. All ethers that are functional group... Problem 14.119EP Problem 14.120EP Problem 14.121EP Problem 14.122EP Problem 14.123EP Problem 14.124EP: How do the chemical reactivities of ethers compare with those of a. alkanes b. alcohols Problem 14.125EP: Explain why ether molecules cannot hydrogen-bond to each other. Problem 14.126EP: How many hydrogen bonds can form between a single ether molecule and water molecules? Problem 14.127EP: Classify each of the following molecular structures as that of a cyclic ether, a noncyclic ether, or... Problem 14.128EP: Classify each of the following molecular structures as that of a cyclic ether, a noncyclic ether, or... Problem 14.129EP Problem 14.130EP Problem 14.131EP Problem 14.132EP: Draw a condensed structural formula for each of the following thiols. a. 1-Propanethiol b.... Problem 14.133EP Problem 14.134EP Problem 14.135EP Problem 14.136EP Problem 14.137EP Problem 14.138EP: For each of the following pairs of compounds, select the compound that has the higher boiling point.... Problem 14.139EP: Assign an IUPAC name to each of the following compounds. a. CH3(CH2)4SH b. CH3(CH2)4OH Problem 14.140EP Problem 14.141EP Problem 14.142EP Problem 14.143EP Problem 14.144EP Problem 14.145EP Problem 14.146EP Problem 14.141EP
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Explain the formula for an aldehyde ?
Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.
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