Following are 'H-NMR and BC-NMR spectral data for compound G (CH0). From this information, deduce the structure of compound G. 'H-NMR 13C-NMR 2.50 (t, 2H) 210.19 126.82 3.05 (t, 2H) 136.64 126.75 3.58 (s, 2H) 133.25 45.02 7.1-7.3 (m, 4H) 128.14 38.11 127.75 28.34

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Following are 'H-NMR and BC-NMR spectral data for compound G (CH0). From
this information, deduce the structure of compound G.
'H-NMR
13C-NMR
2.50 (t, 2H)
210.19 126.82
3.05 (t, 2H)
136.64 126.75
3.58 (s, 2H)
133.25
45.02
7.1-7.3 (m, 4H)
128.14
38.11
127.75
28.34
Transcribed Image Text:Following are 'H-NMR and BC-NMR spectral data for compound G (CH0). From this information, deduce the structure of compound G. 'H-NMR 13C-NMR 2.50 (t, 2H) 210.19 126.82 3.05 (t, 2H) 136.64 126.75 3.58 (s, 2H) 133.25 45.02 7.1-7.3 (m, 4H) 128.14 38.11 127.75 28.34
Expert Solution
Step 1

Calculation of double bond equivalence:

DBE=C+1-H2-X2+N2=10+1-102=6

Thus the given compound must have 6 double bonds or rings or their combination.

 

 

Step 2

Since there is a multiplet of 4 H at 7.1-7.3 ppm, thus the given compound must contain a benzene ring.

The ratio of protons is 2:2:2:4 or 1:1:1:2.

There are 6 signals of 'C' atom within the range of 136.64 to 126.82, thus the given compound must have:

Chemistry homework question answer, step 2, image 1

 

 

 

trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 4 images

Blurred answer
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY