Consider the following two isothermal monatomic ideal gas expansion processes. Path A: Sudden (irreversible) decrease in s pressure from P₁ to P2 (where P2 < P₁). man, Path B: Gradual (reversible) decrease in pressure from P₁ to P2, such that the internal Tenumbu and external pressures remain in equilibrium at every step along the path. (a) Draw a graph of P vs. V illustrating enni, vencens villes evrov the path followed in each of the above Rem processes. (b) Obtain expressions for AU, W, and Q for each of the above processes (express- your results as functions of n, T, P₁, muso en Brinno and/or P₂).

Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter16: Spontaneity, Entropy, And Free Energy
Section: Chapter Questions
Problem 121MP: Consider a sample containing 5.00 moles of a monatomic ideal gas that is taken from state A to state...
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5. Consider the
monatomic ideal gas expansion processes.
510 Path A: Sudden (irreversible) decrease in
Hovs pressure from P₁ to P2 (where P2 < P₁).
Em 201
• Path B: Gradual (reversible) decrease in
outstaamat thaten
pressure from P₁ to P2, such that the internal
sebi pri
and external pressures remain in equilibrium
-lot gril.16
at every step along the path.
Ils ens VEN plas
(quing and e JSW (b)
following
following two isothermal
oitze
(a) Draw a graph of P vs. V illustrating
oth followed in the o
the path followed in each of the above
processes. VRC
moteves processes.
mptay
(b) Obtain expressions for AU, W, and Q for
worllebow
labral
each of the above processes (express
biuos later
your results as functions of n, T, P₁,
and/or P₂).
Brinnos
el to the
montare
Transcribed Image Text:5. Consider the monatomic ideal gas expansion processes. 510 Path A: Sudden (irreversible) decrease in Hovs pressure from P₁ to P2 (where P2 < P₁). Em 201 • Path B: Gradual (reversible) decrease in outstaamat thaten pressure from P₁ to P2, such that the internal sebi pri and external pressures remain in equilibrium -lot gril.16 at every step along the path. Ils ens VEN plas (quing and e JSW (b) following following two isothermal oitze (a) Draw a graph of P vs. V illustrating oth followed in the o the path followed in each of the above processes. VRC moteves processes. mptay (b) Obtain expressions for AU, W, and Q for worllebow labral each of the above processes (express biuos later your results as functions of n, T, P₁, and/or P₂). Brinnos el to the montare
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For both circumstances (reversible and irreversible) what is the change in enthalpy dS for the gas, the surroundings (assuming ideal isothermal bath), and the universe? 

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