For enthalpy 2, the number -63.79 kJ/mol H2SO4 was used for the calculation.  How was this number obtained?  I do not see it on the table here. Was linear interpolation used to determine enthalpy 2?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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For enthalpy 2, the number -63.79 kJ/mol H2SO4 was used for the calculation.  How was this number obtained?  I do not see it on the table here. Was linear interpolation used to determine enthalpy 2?  

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Demonstrate the calculations for enthalpies 1, 2, an...
Mole ratio of water to sulfuric acid (r) = 8.2 (3.33*10-²/4.08*10-³)
From the table of "Integral heats of solution and mixing at 25 °C or 77 °F", the enthalpy of mixing at (r= 8.2)
is -63.79 kJ/mol H₂SO4.
Therefore,
H₂
- 63.79
= 1 lbm solution
ΔΗ =
kJ
mol H₂SO4
Solution
27 Btu + -279.5
■
AH =
The values of enthalpies are,
X
Now the solution is at 77 °F.
Specific enthalpy of 40 wt % H₂SO4 = 0.67 Btu/lbm.°F
The enthalpy of solution at 120 °F is calculated as follows:
H3
1 lbm solution
1200.67dT
1 lb mol H₂SO4
98.08 lb
H
H₂ =
x 0.67
- 279.5
X
H3 = 28.81 Btu
The total enthalpy changes during the heating of solution to 120 °C becomes,
AH₁ + AH₂ + AH3
1 lbm solution
- 55.99
ASK AN EXPERT
1 mol
0.0022046 lbmol
Btu
lbm H₂SO4
77
Btu
lbm solution.°F
Btu
lbm
Btu
-SO4 x 0.4 lbm H₂SO4 + 28.81 Btu
lbm H₂
1 lbm solution
X
x 120 - 77 °F
- 56
Btu
1bm
0.9478 Btu
1 kJ
CHAT
√x MATH SOLVER
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ENG
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Transcribed Image Text:b Answered: Demonstrate the calcu X + 56°F Sunny ✰ bartleby.com/questions-and-answers/demonstrate-the-calculations-for-enthalpies-1-2-and-3./b593a7c4-0e37-4275-af71-29efd148137e Homework help starts here! Q Search = Demonstrate the calculations for enthalpies 1, 2, an... Mole ratio of water to sulfuric acid (r) = 8.2 (3.33*10-²/4.08*10-³) From the table of "Integral heats of solution and mixing at 25 °C or 77 °F", the enthalpy of mixing at (r= 8.2) is -63.79 kJ/mol H₂SO4. Therefore, H₂ - 63.79 = 1 lbm solution ΔΗ = kJ mol H₂SO4 Solution 27 Btu + -279.5 ■ AH = The values of enthalpies are, X Now the solution is at 77 °F. Specific enthalpy of 40 wt % H₂SO4 = 0.67 Btu/lbm.°F The enthalpy of solution at 120 °F is calculated as follows: H3 1 lbm solution 1200.67dT 1 lb mol H₂SO4 98.08 lb H H₂ = x 0.67 - 279.5 X H3 = 28.81 Btu The total enthalpy changes during the heating of solution to 120 °C becomes, AH₁ + AH₂ + AH3 1 lbm solution - 55.99 ASK AN EXPERT 1 mol 0.0022046 lbmol Btu lbm H₂SO4 77 Btu lbm solution.°F Btu lbm Btu -SO4 x 0.4 lbm H₂SO4 + 28.81 Btu lbm H₂ 1 lbm solution X x 120 - 77 °F - 56 Btu 1bm 0.9478 Btu 1 kJ CHAT √x MATH SOLVER ☐ ENG j Paused x : 7:06 AM 5/22/2023
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PDF Elementary Principles of Chemica X PDF *Elementary Principles of Chemic X +
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r(mol H₂O/mol solute)
0.5
1
1.5
2
3
4
5
TABLE B.11 Integral Heats of Solution and Mixing at 25°C²
(AĤs) NaOH(s)
kJ/mol NaOH
10
20
25
30
40
50
100
200
500
1000
2000
5000
10 000
50 000
100 000
500 000
673 of 695
■
(AĤs) HCK(g)
kJ/mol HCI
-26.22
-48.82
-56.85
-61.20
-64.05
-69.49
-71.78
-72.59
-73.00
-73.26
-73.85
-74.20
-74.52
-74.68
-74.82
-74.93
-74.99
-75.08
-75.10
CD
-75.14
28.87
-34.43
-37.74
-42.51
-42.84
42.72
-42.59
-42.51
42.34
-42.26
-42.38
-42.47
-42.55
-42.68
-42.72
-42.80
-42.89
(AĤm) H₂SO4
kJ/mol H₂SO4
-15.73
-28.07
- 36.90
-41.92
- 48.99
- 54.06
-58.03
-67.03
-72.30
-73.34
-73.97
-76.73
-78.57
-84.43
-87.07
-93.64
-95.31
-96.19
"Adapted from J. C. Whitwell and R. K. Toner, Conservation of Mass and Energy, pp. 344-346.
Copyright © 1969 by McGraw-Hill, Inc. Used with permission of McGraw-Hill.
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Transcribed Image Text:||! PDF Elementary Principles of Chemica X PDF *Elementary Principles of Chemic X + 56°F Sunny File | E:/Elementary%20Principles%20of%20Chemical%20Processes,%204th%20Edition%20(%20PDFDrive%20).pdf Draw T Read aloud Q Search r(mol H₂O/mol solute) 0.5 1 1.5 2 3 4 5 TABLE B.11 Integral Heats of Solution and Mixing at 25°C² (AĤs) NaOH(s) kJ/mol NaOH 10 20 25 30 40 50 100 200 500 1000 2000 5000 10 000 50 000 100 000 500 000 673 of 695 ■ (AĤs) HCK(g) kJ/mol HCI -26.22 -48.82 -56.85 -61.20 -64.05 -69.49 -71.78 -72.59 -73.00 -73.26 -73.85 -74.20 -74.52 -74.68 -74.82 -74.93 -74.99 -75.08 -75.10 CD -75.14 28.87 -34.43 -37.74 -42.51 -42.84 42.72 -42.59 -42.51 42.34 -42.26 -42.38 -42.47 -42.55 -42.68 -42.72 -42.80 -42.89 (AĤm) H₂SO4 kJ/mol H₂SO4 -15.73 -28.07 - 36.90 -41.92 - 48.99 - 54.06 -58.03 -67.03 -72.30 -73.34 -73.97 -76.73 -78.57 -84.43 -87.07 -93.64 -95.31 -96.19 "Adapted from J. C. Whitwell and R. K. Toner, Conservation of Mass and Energy, pp. 344-346. Copyright © 1969 by McGraw-Hill, Inc. Used with permission of McGraw-Hill. {" J 63 60 D ENG Sign in (0) + O 7:07 AM 5/22/2023
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