For the analysis below, find one step within design of experiment, interpretation and calculation of the given situation that is not correct.  Write the incorrect step, and state why it is not correct.  Write how you will change the step to make it correct.  Why do you think he made the mistake  ? A student will use a solution containing the complex formed between Bi(III) and thiourea (which has a molar absorptivity of 9.32 X 103 L cm-1 mol-1 at 470 nm) for his thesis experiment (investigation of its optical properties).  To know the concentration, he used a calibrated UV-Vis spectrophotometer  and 1.00-cm cell , and obtained absorbance of 0.528.  To determine concentration, he multiplied  molar absorptivity  by MM of  thiourea complex (MM: 437.3 g/mol) and used Beer’s law.  The concentration he obtained is 1.99 X 10-7 M solution.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
ChapterA1: Evaluation Of Analytical Data
Section: Chapter Questions
Problem A1.23QAP
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For the analysis below, find one step within design of experiment, interpretation and calculation of the given situation that is not correct.  Write the incorrect step, and state why it is not correct.  Write how you will change the step to make it correct.  Why do you think he made the mistake  ?

A student will use a solution containing the complex formed between Bi(III) and thiourea (which has a molar absorptivity of 9.32 X 103 L cm-1 mol-1 at 470 nm) for his thesis experiment (investigation of its optical properties).  To know the concentration, he used a calibrated UV-Vis spectrophotometer  and 1.00-cm cell , and obtained absorbance of 0.528.  To determine concentration, he multiplied  molar absorptivity  by MM of  thiourea complex (MM: 437.3 g/mol) and used Beer’s law.  The concentration he obtained is 1.99 X 10-7 M solution.

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