For the buffer system in Problem no. 1, what will be the pH when (a) 15.0 ml of 0.500 M HCl and (b) when 15.0 ml of 0.750 M NaOH is added to the buffer?

Appl Of Ms Excel In Analytical Chemistry
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ISBN:9781285686691
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Chapter8: Polyfunctional Acids And Bases
Section: Chapter Questions
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For the buffer system in Problem no. 1, what will be the pH when (a) 15.0 ml of 0.500 M HCl and (b) when 15.0 ml of 0.750 M NaOH is added to the buffer?

Accerding to Hendeeson Hasselbalch equation 7
pH= pka+ log (conjugate Ber)
Step 2
ro ef mdes of conjugate
20 X 3
= 60 mmoles
no.
base
%3D
·e moles of acid
50 X 2
100 mmoles
no:
%3D
Ka = 4.30 X 1o-7
%3D
Ka
(4:30 X10*
6.3665
pha=
PH = 6.3665 t
log Go
100
= 6.335 -0.2218
pH = 6:1447
or
Transcribed Image Text:Accerding to Hendeeson Hasselbalch equation 7 pH= pka+ log (conjugate Ber) Step 2 ro ef mdes of conjugate 20 X 3 = 60 mmoles no. base %3D ·e moles of acid 50 X 2 100 mmoles no: %3D Ka = 4.30 X 1o-7 %3D Ka (4:30 X10* 6.3665 pha= PH = 6.3665 t log Go 100 = 6.335 -0.2218 pH = 6:1447 or
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