For the decomposition of the acceptor---nitrate complex: acceptor•NO3 - acceptor + NO3 the rate constant at 321 K is k=5.10x10-4 s-1. What is the order of the reaction? O 2nd order O 3rd order O Oth order O 1st order

Fundamentals Of Analytical Chemistry
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Chapter10: Effect Of Electrolytes On Chemical Equilibria
Section: Chapter Questions
Problem 10.4QAP
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Halogen bonding is an intermolecular force (not introduced to you in CHEM
1050), like hydrogen bonding and dispersion forces. They occur when a
halogen atom, such is iodine has a small positive charge and interacts with
an electron rich species such as an electronegative atom or an anion. For
example, a complex between the iodide anion and a bidentate (double)
acceptor is shown below.
ассeptor
halogen bonds
anion
As the first step in determining the chemical nature of these complexes, the
gas-phase decomposition reactions of these types of complexes were studied
in the Department of Chemistry here at Memorial. (Phys. Chem. Chem. Phys.
2013, 15, 7647).
Transcribed Image Text:Halogen bonding is an intermolecular force (not introduced to you in CHEM 1050), like hydrogen bonding and dispersion forces. They occur when a halogen atom, such is iodine has a small positive charge and interacts with an electron rich species such as an electronegative atom or an anion. For example, a complex between the iodide anion and a bidentate (double) acceptor is shown below. ассeptor halogen bonds anion As the first step in determining the chemical nature of these complexes, the gas-phase decomposition reactions of these types of complexes were studied in the Department of Chemistry here at Memorial. (Phys. Chem. Chem. Phys. 2013, 15, 7647).
For the decomposition of the acceptor---nitrate complex:
acceptor•NO3- acceptor + NO3
the rate constant at 321 K is k=5.10x10-4 s-1. What is the order of the reaction?
O 2nd order
O 3rd order
O Oth order
O 1st order
Transcribed Image Text:For the decomposition of the acceptor---nitrate complex: acceptor•NO3- acceptor + NO3 the rate constant at 321 K is k=5.10x10-4 s-1. What is the order of the reaction? O 2nd order O 3rd order O Oth order O 1st order
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