For the gas phase decomposition of ethyl chloroformate, CICOOC₂H5→ C₂H5 Cl + CO2 the rate constant in s¹ has been determined at several temperatures. When In k is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of -1.48 x 104 K and a y-intercept of 24.6. The value of the rate constant for the gas phase decomposition of ethyl chloroformate at 465 K is S-¹.

For the gas phase decomposition of ethyl chloroformate, CICOOC₂H5→ C₂H5 Cl + CO2 the rate constant in s¹ has been determined at several temperatures. When In k is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of -1.48 x 104 K and a y-intercept of 24.6. The value of the rate constant for the gas phase decomposition of ethyl chloroformate at 465 K is S-¹.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter20: Kinetics

Section: Chapter Questions

Problem 20.60E

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