Given that the internal energy U of blackbody radiation in a cavity of volume V at temperature T is given by U = aVT*, where a is independent of both V and T, show by thermodynamic reasoning that the free energy, F, and the entropy, S, of the radiation must have the forms: 1 P = --aVT* +Tf(V) » 4 S = ; aVT - f(V) , | where f(V) is an unknown function of V. Assuming S vanishes at T = 0 (because there is no radiation) or assuming the third law of thermodynamics: as as T +0 av T show that the radiation pressure is given by 1 U P = 3 V
Given that the internal energy U of blackbody radiation in a cavity of volume V at temperature T is given by U = aVT*, where a is independent of both V and T, show by thermodynamic reasoning that the free energy, F, and the entropy, S, of the radiation must have the forms: 1 P = --aVT* +Tf(V) » 4 S = ; aVT - f(V) , | where f(V) is an unknown function of V. Assuming S vanishes at T = 0 (because there is no radiation) or assuming the third law of thermodynamics: as as T +0 av T show that the radiation pressure is given by 1 U P = 3 V
Modern Physics
3rd Edition
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Chapter8: Quantum Mechanics In Three Dimensions
Section: Chapter Questions
Problem 15P
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