Given these data for the acid-catalyzed reaction in question 22, find the rate law. (RCOOH], M (R’OH], M (HA], M Initial Rate, M•min"' 0.35 0.35 0.50 4.60 0.62 0.35 0.50 8.14 0.35 0.81 0.50 10.6 0.35 0.50 0.75 9.84 Rate = k[RCOOH][R'OH] Rate = k[RCOOH][R'OH][HA] Rate = k[RCOOR']/{[RCOOH][R'OH]} Rate = k[R'OH] Rate = k[RCOOH] oo00 o

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter31: Synthetic Polymers
Section31.SE: Something Extra
Problem 21AP
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22.
Below are the reaction steps in a certain polymerization process,
which may occur by either an uncatalyzed or an acid-catalyzed
pathway.
0–H
ki
- R-C+
k2
R-
-С-о—н
+ HA
A-
0–H
Group 1
0–H
0–H
k3
R-Ċ+
A-
-0–H
R-Ć-
0–H
k4
0–H
R-ó+
A-
Group 2
H
0–H
||
-C-0–R'
R-
ks
R–C-0¬H
+ Hо + НА
R-ó+
A
Group 3
23.
Given these data for the acid-catalyzed reaction in question 22, find
the rate law.
(RCOOH], M
[R’OH], M
[HA], M
Initial Rate, M-min
0.35
0.35
0.50
4.60
0.62
0.35
0.50
8.14
0.35
0.81
0.50
10.6
0.35
0.50
0.75
9.84
Rate =
k[RCOOH][R'OH]
Rate =
k[RCOOH][R'OH][HA]
Rate =
k[RCOOR']/{[RCOOH][R'OH]}
Rate =
k[R'OH]
Rate = k[RCOOH]
Transcribed Image Text:22. Below are the reaction steps in a certain polymerization process, which may occur by either an uncatalyzed or an acid-catalyzed pathway. 0–H ki - R-C+ k2 R- -С-о—н + HA A- 0–H Group 1 0–H 0–H k3 R-Ċ+ A- -0–H R-Ć- 0–H k4 0–H R-ó+ A- Group 2 H 0–H || -C-0–R' R- ks R–C-0¬H + Hо + НА R-ó+ A Group 3 23. Given these data for the acid-catalyzed reaction in question 22, find the rate law. (RCOOH], M [R’OH], M [HA], M Initial Rate, M-min 0.35 0.35 0.50 4.60 0.62 0.35 0.50 8.14 0.35 0.81 0.50 10.6 0.35 0.50 0.75 9.84 Rate = k[RCOOH][R'OH] Rate = k[RCOOH][R'OH][HA] Rate = k[RCOOR']/{[RCOOH][R'OH]} Rate = k[R'OH] Rate = k[RCOOH]
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