H- -CI H- -OH но но. ČH2OH ČH;OH CH,OH I II III A) I, II and III are diasteromers B) I and II are diastereomers, I and III are enantiomers C) I, II and III are different compounds that are not isomers. D) I and II are enantiomers, I and III are diastereomers 19) In the following reaction, NaSH, solvent Br A) The Br is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprotic solvent. B) The F is replaced by a -SH, the reaction goes via SN² and is faster in a polar aprotic solvent. C) The Br is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic solvent. D) The F is replaced by a –SH, the reaction goes via SN' and is faster in a polar protic solvent. E) None of these is true 20) In the following reaction, identify the major product. OH KHSO, OH он

General, Organic, and Biological Chemistry
7th Edition
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:H. Stephen Stoker
Chapter18: Carbohydrates
Section: Chapter Questions
Problem 18.32EP
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18) Which of the following statements is true ?
CHO
CHO
сно
:CI
CI-
H-
CI
H-
-OH
но
-H
HO
CH2OH
CH2OH
CH,OH
I
II
III
A) I, II and III are diasteromers
B) I and II are diastereomers, I and III are enantiomers
C) I, II and III are different compounds that are not isomers.
D) I and II are enantiomers, I and III are diastereomers
19) In the following reaction,
NaSH, solvent
Br
A) The Br is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprotic
solvent.
B) The F is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprotic
solvent.
C) The Br is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic
solvent.
D) The F is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic
solvent.
E) None of these is true
20) In the following reaction, identify the major product.
Он
KHSO,
OH
OH
7
Transcribed Image Text:18) Which of the following statements is true ? CHO CHO сно :CI CI- H- CI H- -OH но -H HO CH2OH CH2OH CH,OH I II III A) I, II and III are diasteromers B) I and II are diastereomers, I and III are enantiomers C) I, II and III are different compounds that are not isomers. D) I and II are enantiomers, I and III are diastereomers 19) In the following reaction, NaSH, solvent Br A) The Br is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprotic solvent. B) The F is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprotic solvent. C) The Br is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic solvent. D) The F is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic solvent. E) None of these is true 20) In the following reaction, identify the major product. Он KHSO, OH OH 7
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