H + H,N-NH, H CH12N2 а. 2.0 equiv. NH2 H* H + b. H2N 2.0 equiv. NH, NH2

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 41AP: In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following...
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Predict the major product of the following reactions. The formulae of the products are given in bold.

 

 

H*
H,N-NH,
H.
a.
CH12N2
2.0 equiv.
NH2
H*
H.
H2N
C20H16N2
b.
2.0 equiv.
NH2
H
C.
NH2
H
ZHN
C42H43N
e.
H,N-NH2
+ H2N-OH
H*
C;H,NO
are more stable than those in other reactions. Why?
The products in
g.
d, e and f
f.
Transcribed Image Text:H* H,N-NH, H. a. CH12N2 2.0 equiv. NH2 H* H. H2N C20H16N2 b. 2.0 equiv. NH2 H C. NH2 H ZHN C42H43N e. H,N-NH2 + H2N-OH H* C;H,NO are more stable than those in other reactions. Why? The products in g. d, e and f f.
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