Part c Follow the detailed instructions provided in each of the subsections (a-c):a) Fill in the following reaction scheme by drawing the structure of intermediate 3 andproducts 4-5. Chemical formulas have been added as guidance.H,CCIH,NCH3H, SO,2CH3C,H,,NO,C,H,NO,CH,OH1- HCIH203Step 1Step 2H2NCH,OHC,H,,N,O,Assign the absolute stereochemistry of the stereogenic centre in compound 1.b) If the methyl ester in compound 1 was replaced by a carboxylic acid, compound 1 couldreact with itself. Can you predict which product will be formed?H,NHO.CH2C,H;NO,Step 17c) Using curly arrows, draw the mechanism of Step 2.

The mechanism of step 2 can be describe as follows. First of all Protonation of oxygen on ester side…

Answered: H,C CI H2N. CH3 H,SO, C,H,,NO, C,H,NO,…

Science

Chemistry

H,C CI H2N. CH3 H,SO, C,H,,NO, C,H,NO, + CH,OH - HCI H,0 4. Step 1 Step 2 2.

Pushing Electrons

4th Edition

ISBN:9781133951889

Author:Weeks, Daniel P.

Publisher:Weeks, Daniel P.

Chapter1: Lewis Structures

Section: Chapter Questions

Problem 73EQ

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Question

Part c

Follow the detailed instructions provided in each of the subsections (a-c):
a) Fill in the following reaction scheme by drawing the structure of intermediate 3 and
products 4-5. Chemical formulas have been added as guidance.
H,C
CI
H,N
CH3
H, SO,
2
CH3
C,H,,NO,
C,H,NO,
CH,OH
1
- HCI
H20
3
Step 1
Step 2
H2N
CH,
OH
C,H,,N,O,
Assign the absolute stereochemistry of the stereogenic centre in compound 1.
b) If the methyl ester in compound 1 was replaced by a carboxylic acid, compound 1 could
react with itself. Can you predict which product will be formed?
H,N
HO.
CH2
C,H;NO,
Step 1
7
c) Using curly arrows, draw the mechanism of Step 2.

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