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Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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5) What Newman projection (through the highlighted bond) represents the lowest energy conformation
for the molecule shown?
CI
CI
Ha
H.
CI
6) What is(are) the major(s) in this reaction?
Conc. HCI
a) A b) B c) C d) D e) A & B f) C& D
Transcribed Image Text:5) What Newman projection (through the highlighted bond) represents the lowest energy conformation for the molecule shown? CI CI Ha H. CI 6) What is(are) the major(s) in this reaction? Conc. HCI a) A b) B c) C d) D e) A & B f) C& D
4) what's the major and minor product for this reaction?
Br
Na OH
->
OH
Transcribed Image Text:4) what's the major and minor product for this reaction? Br Na OH -> OH
Expert Solution
Step 1 . solution of 5 & 6

5)Newmann projection- we have to visualize the structure of the compound from front to back carbon bonds.

eclipsed conformation of Newmann projection the groups are more closer, create more torsional strain.

staggered conformation of Newmann projection the groups are far away from each other, create less torsional strain.

Answer-In conformation A- there is no torsional strain between the H and Cl group, and the H and t-butyl group, due to this there is less energy and higher stability.

6) step 1. protonation of alcohol by Strong acid HCl.

step 2. loss of leaving group H2O, forming 20-carbocation( less stable)

Step 3.Rearrangement- 1,2-Me shift occurs for the formation of 30-carbocation( more stable).

Step 4. a nucleophilic attack by Cl- occurs from both sides, the formation of the racemic mixture as a product.

Answer- e) A & B

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