need help with problems 4. And 5.  Thank you!

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter20: Acidity And Pka Of Phenols
Section: Chapter Questions
Problem 23CTQ
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I need help with problems 4. And 5.  Thank you!

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